SIST EN 16167:2018+AC:2019

Soil, treated biowaste and sludge - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)

This draft European Standard specifies a method for quantitative determination of seven selected polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 and PCB180) in sludge, treated biowaste and soil using GC-MS and GC-ECD (see Table 2).
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this European Standard, limit of application of 1 μg/kg (expressed as dry matter) can be achieved.
Sludge and treated biowaste may differ in properties and also in the expected contamination levels of PCBs and presence of interfering substances. These differences make it impossible to describe one general procedure. This European Standard contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.

Boden, behandelter Bioabfall und Schlamm - Bestimmung von polychlorierten Biphenylen (PCB) mittels Gaschromatographie mit Massenspektrometrie-Kopplung (GC-MS) und Gaschromatographie mit Elektroneneinfangdetektion (GC-ECD)

Die vorliegende Europäische Norm legt ein Verfahren für die quantitative Bestimmung von sieben ausgewählten polychlorierten Biphenylen (PCB 28, PCB 52, PCB 101, PCB 118, PCB 138, PCB 153 und PCB 180) in Schlamm, behandeltem Bioabfall und Boden unter Anwendung der GC MS und GC ECD fest (siehe Tabelle 2).

Sols, biodéchets traités et boues - Dosage des polychlorobiphényles (PCBs) par chromatographie en phase gazeuse-spectrométrie gazeuse couplée avec un détecteur de masse (CG-SM) ou un détecteur par capture d'électrons (CG-ECD)

Tla, obdelani biološki odpadki in blato - Določevanje polikloriranih bifenilov (PCB) s plinsko kromatografijo z masno selektivnim detektorjem (GC/MS) in s plinsko kromatografijo z detektorjem z zajetjem elektronov (GC/ECD) (vključno s popravkom AC)

Ta osnutek evropskega standarda določa metodo za kvantitativno določevanje sedmih izbranih polikloriranih bifenilov (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 in PCB180) v blatu, obdelanih bioloških odpadkih ter tleh z metodama GC-MS in GC-ECD (glej preglednico 2).
Meja detekcije je odvisna od determinant, uporabljene opreme, kakovosti kemikalij, uporabljenih za ekstrakcijo vzorca in očiščenje izvlečka.
Pod pogoji, določenimi v tem evropskem standardu, je mogoče doseči mejo uporabe 1 μg/kg (izraženo kot suha snov).
Blato in obdelani biološki odpadki se lahko razlikujejo glede lastnosti, predvidenih stopenj onesnaženja s polikloriranimi bifenili ter prisotnosti motečih snovi. Zaradi teh razlik ni možen opis enotnega splošnega postopka. Ta evropski standard vključuje tabele odločanja, ki temeljijo na lastnostih vzorca, ter postopek za ekstrakcijo in očiščenje, ki ga je treba uporabiti.

General Information

• Status: Withdrawn
• Publication Date: 10-Feb-2019
• Withdrawal Date: 23-Sep-2020
• ICS: 13.030.20 - Liquid wastes. Sludge
• ICS: 13.080.10 - Chemical characteristics of soils
• ICS: 71.040.50 - Physicochemical methods of analysis
• Technical Committee: KAT - Soil quality
• Current Stage: 9900 - Withdrawal (Adopted Project)
• Start Date: 23-Sep-2020
• Due Date: 16-Oct-2020
• Completion Date: 24-Sep-2020
• Directive: 86/278/EEC - Protection of the environment, and in particular of the soil, when sewage sludge is used in agriculture
• Ref Project: EN 16167:2018+AC:2019 - Soil, treated biowaste and sludge - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)

Relations

• Replaced By: SIST EN 17322:2020 - Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-ECD)
• Effective Date: 01-Nov-2020
• Amends: SIST EN 16167:2018 - Soil, treated biowaste and sludge - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)
• Effective Date: 01-Mar-2019

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN 16167:2018+AC:2019
01-marec-2019
1DGRPHãþD
SIST EN 16167:2018
7ODREGHODQLELRORãNLRGSDGNLLQEODWR'RORþHYDQMHSROLNORULUDQLKELIHQLORY3&%
VSOLQVNRNURPDWRJUDILMR]PDVQRVHOHNWLYQLPGHWHNWRUMHP*&06LQVSOLQVNR
NURPDWRJUDILMR]GHWHNWRUMHP]]DMHWMHPHOHNWURQRY*&(&'YNOMXþQRV
SRSUDYNRP$&
Soil, treated biowaste and sludge - Determination of polychlorinated biphenyls (PCB) by
gas chromatography with mass selective detection (GC-MS) and gas chromatography
with electron-capture detection (GC-ECD)
Boden, behandelter Bioabfall und Schlamm - Bestimmung von polychlorierten
Biphenylen (PCB) mittels Gaschromatographie mit Massenspektrometrie-Kopplung (GC-
MS) und Gaschromatographie mit Elektroneneinfangdetektion (GC-ECD)
Sols, biodéchets traités et boues - Dosage des polychlorobiphényles (PCBs) par
chromatographie en phase gazeuse-spectrométrie gazeuse couplée avec un détecteur
de masse (CG-SM) ou un détecteur par capture d'électrons (CG-ECD)
Ta slovenski standard je istoveten z: EN 16167:2018+AC:2019
ICS:
13.030.20 7HNRþLRGSDGNL%ODWR Liquid wastes. Sludge
13.080.10 .HPLMVNH]QDþLOQRVWLWDO Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 16167:2018+AC:2019 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 16167:2018+AC:2019

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SIST EN 16167:2018+AC:2019


EN 16167:2018+AC
EUROPEAN STANDARD

NORME EUROPÉENNE

January 2019
EUROPÄISCHE NORM
ICS 13.030.01; 13.080.10 Supersedes EN 16167:2018
English Version

Soil, treated biowaste and sludge - Determination of
polychlorinated biphenyls (PCB) by gas chromatography
with mass selective detection (GC-MS) and gas
chromatography with electron-capture detection (GC-
ECD)
Sols, biodéchets traités et boues - Dosage des Boden, behandelter Bioabfall und Schlamm -
polychlorobiphényles (PCBs) par chromatographie en Bestimmung von polychlorierten Biphenylen (PCB)
phase gazeuse-spectrométrie gazeuse couplée avec un mittels Gaschromatographie mit
détecteur de masse (CG-SM) ou un détecteur par Massenspektrometrie-Kopplung (GC-MS) und
capture d'électrons (CG-ECD) Gaschromatographie mit Elektroneneinfangdetektion
(GC-ECD)
This European Standard was approved by CEN on 20 March 2018 and includes the Corrigendum issued by CEN on 30 January
2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATIO N

EUROPÄISCHES KOMITEE FÜR NORMUN G

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 16167:2018+AC:2019 E
worldwide for CEN national Members.

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SIST EN 16167:2018+AC:2019
EN 16167:2018+AC:2019 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Principle .
...