B10.02 - Zirconium and Hafnium

ABSTRACT
This specification covers the standard requirements for two grades of wrought hafnium and hafnium alloy strip, sheet, and plate: Grade R1 for nuclear applications and Grade R3 for commercial applications. The materials shall be made from ingots that are produced in a furnace by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of these three methods, or other melting process conventionally used for reactive metals. The various mill products shall be formed with the conventional extrusion, forging, or rolling equipment normally found in primary ferrous and nonferrous plants. The sheet, strip, and plate shall either be hot-rolled or cold-rolled and shall be supplied in the recrystallized annealed condition. Grades R1 and R3 metal shall conform to the chemical composition requirements for aluminum, carbon, chromium, copper, hydrogen, iron, molybdenum, nickel, niobium, nitrogen, oxygen, silicon, tantalum, tin, titanium, tungsten, uranium, vanadium, zirconium, and hafnium as shall be determined by chemical analysis. Mechanical properties, which shall be determined by tension tests both in longitudinal and transverse direction, shall meet the prescribed tensile strength, yield strength, and elongation requirements. Corrosion testing in water shall also be performed to determine the corrosion resistance of the materials.
SCOPE
1.1 This specification covers two grades of wrought hafnium and hafnium alloy strip, sheet, and plate as follows:  
1.1.1 Grade R1 for nuclear applications, and  
1.1.2 Grade R3 for commercial applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers three grades of zirconium and zirconium alloy bar and wire as grade R60702, unalloyed zirconium; grade R60704, zirconium-tin; and grade R60705, zirconium-niobium. The chemical composition; and mechanical properties requirements, such as tensile strength, yield strength, and elongation; are detailed.
SCOPE
1.1 This specification2 covers three grades of zirconium and zirconium alloy bar and wire.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test methods portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers UNS R60001, R60802, R60804, and R60901 wrought zirconium and zirconium alloy bars, rods, and wires. All material grades covered should conform to the required chemical composition requirements. Elements that are intentionally added to the melt should be identified, analyzed and reported in the chemical analysis. The zirconium and zirconium alloys should be made from ingots produced by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of the three methods, or other melting processes conventionally used for reactive metals. All processes should be performed in furnaces specifically for reactive metals. Mill products included in this specification should be formed with conventional extrusion, forging, or rolling equipment that is used in primary ferrous and nonferrous plants. The cold worked and annealed materials should be in fully annealed condition unless otherwise specified. Hot worked shapes should be furnished in not descaled, mechanically descaled, or mechanically descaled and pickled finish, while cold-worked shapes should be furnished in cold-worked, ground, or pickled finish.
SCOPE
1.1 This specification covers four grades of wrought zirconium and zirconium alloy bars, rod, and wire as follows:  
1.1.1 R60001—Unalloyed grade,  
1.1.2 R60802—Zirconium-Tin alloy (Zircaloy 2),  
1.1.3 R60804—Zirconium-Tin alloy (Zircaloy 4), and  
1.1.4 R60901—Zirconium-Niobium alloy.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the three grades of zirconium and zirconium alloy seamless and welded tubes. The tubes are furnished in three grades as Grade R60702 which is an unalloyed zirconium, Grade R60704 which is zirconium-tin alloy, and Grade R60705 which is zirconium-niobium alloy. Seamless tube shall be made by any seamless method. Welded tube shall be made from sheet or strip by an automatic arc-welding process or other method of welding. Filler metal shall not be used. The material shall conform to the required chemical compostion for zirconium, hafnium, iron, chromium, tin, hydrogen, nitrogen, carbon, niobium, and oxygen. The materials shall conform to the required tensile properties such as tensile strength, yield strength, and elongation.
SCOPE
1.1 This specification2 covers two grades of zirconium and zirconium alloy seamless and welded tubes.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.  
1.3 The following precautionary caveat pertains only to the test methods portion of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the standard requirements for wrought zirconium and zirconium alloy seamless and welded tubes for nuclear applications except for nuclear fuel cladding. Five grades of reactor grade zirconium and zirconium alloys with R60001, R60802, R60804, R60901, and R60904 UNS number designations are described. Material shall be made from ingots produced by vacuum arc melting, electron beam melting, or other melting process to be carried out in furnaces conventionally used for reactive metals. Seamless tubes may be made by billet extrusion with subsequent cold working, by drawing, swaging, or rocking, with intermediate annealing. Welded tubing shall be made from flat-rolled products by an automatic or semiautomatic welding process with no addition of filler metal and shall be cold reduced by drawing, swaging, or rocking. The products shall be in the recrystallized or cold-worked and stress-relieved conditions and shall be furnished by as-cold reducing, pickling, grounding, polishing, or end-saw cutting, machining, or shearing. Chemical and product analysis shall be performed on the materials which shall meet the chemical composition requirements for tin, iron, chromium, nickel, niobium, oxygen, and other impurity elements. The tensile properties shall be determined by a tensile test method and shall conform to the tensile strength, yield strength, and elongation limits. Steam and water corrosion tests and hydrostatic test shall be conducted to determine the acceptance criteria for corrosion and internal hydrostatic pressure, respectively. Burst properties, contractile strain ratio, grain size, and hydride orientation of the finished tubing shall also be determined.
SIGNIFICANCE AND USE
16.1 For the purpose of determining compliance with the specified limits of property requirements, an observed value or a calculated value shall be rounded in accordance with the rounding method of Practice E29.    
Test  
Rounded Units for Observed
or Calculated Value  
Chemical composition, tolerance
(when expressed in decimals)  
nearest unit in the last right hand place of figures of the specified limit  
Tensile strength and yield strength  
nearest 1000 psi (10 MPa)  
Elongation  
nearest 1 %
SCOPE
1.1 This specification covers seamless and welded wrought zirconium and zirconium-alloy tubes for nuclear application. Nuclear fuel cladding is covered in Specification B811.  
1.2 Five grades of reactor grade zirconium and zirconium alloys suitable for nuclear application are described.  
1.2.1 The present UNS numbers designated for the five grades are given in Table 1.  
1.3 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.4 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers seamless wrought zirconium-alloy tubes for nuclear reactor fuel cladding application. Two grades of reactor grade zirconium alloys are described. Tubes covered by this specification shall be made from ingots produced by multiple vacuum arc or electron beam melting in furnaces of a type conventionally used for reactive materials. The tubes shall conform to the requirements for chemical composition prescribed. Recrsytallisation annealed tubes shall conform to the requirements for mechanical properties at room temperature prescribed. The tension test shall be conducted. Yield strength and tension properties shall be determined. Burst testing, when specified, shall be performed at room temperature on finished tubing.
SCOPE
1.1 This specification covers seamless wrought zirconium-alloy tubes for nuclear fuel cladding application, in the outside diameter (OD) size range of 0.200 in. (5.1 mm) to 0.650 in. (16.5 mm) and wall thickness range of 0.010 in. (0.25 mm) to 0.035 in. (0.89 mm).  
1.2 Two grades of reactor grade zirconium alloys are described.  
1.2.1 The present UNS numbers designated for the two grades are given in Table 1.  
1.3 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.4 The following precautionary caveat pertains only to the test method portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers zirconium and zirconium-alloy castings for general corrosion-resistant and industrial applications. Material for this specification shall be melted by conventional processes used for reactive metals. Typical methods include the consumable electrode and inductoslag melting processes. The material shall conform to the required chemical composition for zirconium, hafnium, iron, chromium, hydrogen, nitrogen, carbon, oxygen, phosphorus, tin, and niobium. Product analysis and heat treatment shall be performed on the material, and shall conform within the specified check analysis tolerances.
SCOPE
1.1 This specification covers zirconium and zirconium-alloy castings for general corrosion-resistant and industrial applications.  
1.2 The values stated in either inch-pound units or SI units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system shall be used independently of each other. Combining values from the two systems may result in nonconformance with this specification.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the six grades of zirconium and zirconium alloy ingots: Grade R60700, Grade R60702, Grade R60703, Grade R60704, Grade R60705, and Grade R60706. These materials shall be manufactured by electron beam, vacuum, or inert atmosphere melting in furnaces. The material shall form to the required chemical composition of zirconium, hafnium, iron, chromium, tin, hydrogen, nitrogen, carbon, niobium, and oxygen. Check analysis shall be performed. The following test methods shall be done: ultrasonic test and chemical test.
SCOPE
1.1 This specification covers six grades of zirconium ingots.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 The following precautionary caveat pertains only to the test method portion, Section 10, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers five grades of zirconium strip, sheet, and plate. These are low oxygen zirconium (Grade R60700), unalloyed zirconium (Grade R60702), zirconium-tin (Grade R60704), zirconium-niobium (Grade R60705), and zirconium-niobium (Grade R60706). The materials shall be made from ingots that are produced by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of these three methods or other melting processes conventionally used for reactive metals. All processes to be done in furnaces usually used for reactive metals. The various mill products covered by this specification are formed with the conventional extrusion, forging, or rolling equipment normally found in primary ferrous and nonferrous plants. The strip, sheet, and plate shall be supplied in the recrystallized annealed condition unless otherwise specified in the purchase order. The materials shall be subjected to chemical analysis and tensile strength, yield strength, elongation, bend, and flatness tests.
SCOPE
1.1 This specification2 covers five grades of zirconium strip, sheet, and plate.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification:  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers hot- and cold-rolled zirconium and zirconium alloy sheet, strip, and plate.
SCOPE
1.1 This specification covers hot- and cold-rolled zirconium and zirconium alloy sheet, strip, and plate.  
1.2 One unalloyed and three alloys for use in nuclear applications are described.  
1.3 The products covered in this specification include the following forms and sizes:  
1.3.1 Sheet, 24 in. [600 mm] or more in width; under 0.187 in. [4.8 mm] in thickness,  
1.3.2 Strip, less than 24 in. [600 mm] in width; under 0.187 in. [4.8 mm] in thickness, and  
1.3.3 Plate, over 10 in. [250 mm] in width; 0.187 in. [4.8 mm] and over in thickness.
Note 1: Material over 0.187 in. [4.8 mm] in thickness and less than 10 in. [250 mm] wide is covered as bar in Specification B351/B351M.  
1.4 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This practice covers a cleaning and de-scaling procedure useful to producers, users, and fabricators of zirconium and zirconium alloys for the removal of ordinary shop soils, oxides, and scales resulting from heat treatment operations and foreign substances present as surface contaminants. Grease, oil, and lubricants employed in machining, forming, and fabricating operations on zirconium and zirconium alloys should be removed by employing one of the methods or a combination of methods: alkaline or emulsion soak-type cleaners, ultrasonic cleaning, acetone, citrus based cleaners, or safety solvent immersion washing or vapor degreasing, or electrolytic alkaline cleaning system. Mechanical de-scaling methods such as sandblasting, shot blasting, and vapor blasting may be used to remove hot work scales and lubricants from zirconium surfaces if followed by thorough conditioning and cleaning. Aluminum oxide, silicon carbide, silica sand, zircon sand, and steel grit are acceptable media for mechanical de-scaling. Recommended post treatment of shot or abrasive blasted zirconium surfaces may include acid pickling to ensure complete removal of metallic iron, oxide, scale, and other surface contaminants. Visual inspection of material cleaned in accordance with this practice should show no evidence of paint, oil, grease, glass, graphite, lubricant, scale, abrasive, iron, or other forms of contamination.
SCOPE
1.1 This practice covers a cleaning and descaling procedure useful to producers, users, and fabricators of zirconium and zirconium alloys for the removal of ordinary shop soils, oxides, and scales resulting from heat treatment operations and foreign substances present as surface contaminants.  
1.2 It is not intended that these procedures become mandatory for removal of any of the indicated soils but rather serve as a guide when zirconium and zirconium alloys are being processed in the wrought, cast, or fabricated form.  
1.3 It is the intent that these soils be removed prior to chemical milling, joining, plating, welding, fabrication, and in any situation where foreign substances interfere with the corrosion resistance, stability, and quality of the finished product.  
1.4 Unless a single unit is used, for example, solution concentrations in g/l, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Sections 3 and 7.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers hot-, cold-, or both hot- and cold-rolled hafnium rods and wires in either one of two grades. All grades should be in the recrystallization annealed condition unless specified otherwise. The materials should be made from ingots produced by vacuum melting in an electron beam or consumable arc furnaces, or both, of a type conventionally used for reactive metals. Samples for chemical composition tests should be taken from the top, middle, and bottom of the ingots. The requirements for mechanical properties do not apply to wires. Corrosion tests shall be done in water. All rods should be furnished in mechanically descaled and pickled, centerless ground and pickled, or centerless ground, pickled, and oxidized surface finish, while wires should be furnished in either conditioned and pickled or conditioned, pickled, and oxidized surface finish.
SIGNIFICANCE AND USE
15.1 For the purpose of determining compliance with the specified limits for requirements of the properties listed in the following table, an observed value or a calculated value shall be rounded as indicated in accordance with the rounding methods of Practice E29.    
Property  
Rounded Unit for Observed
or Calculated Value  
Chemical composition, and tolerances (when expressed as decimals)  
nearest unit in the last right-hand place of figures of the specified limit  
Tensile strength and yield strength  
nearest 1000 psi (10 MPa)  
Elongation  
nearest 1 %
SCOPE
1.1 This specification covers hot- or cold-worked hafnium rod and wire.  
1.2 This specification contains two material grades, one specifically for nuclear applications (Grade R1) and one for commercial alloying applications (Grade R3).  
1.3 The products covered include the following:  
1.3.1 Rod 3/8 to 1 in. (9.5 to 25 mm) in diameter.  
1.3.2 Wire less than 3/8 in. (9.5 mm) in diameter.  
1.4 Unless a single unit is used, for example, corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers one grade of virgin zirconium metal commonly designated as sponge because of its porous, sponge-like texture, but it may also take other forms such as chunklets. The one grade described is designated as Reactor Grade R60001, suitable for use in nuclear applications. The main characteristic of the reactor grade is its low nuclear cross section as achieved by removal of hafnium. Zirconium metal is usually prepared by reduction of zirconium tetrachloride, and gets its physical characteristics from the processes involved in production. These characteristics may be expected to vary greatly with manufacturing methods. Only virgin zirconium metal, in identified, uniform, well-mixed blends, shall be used. The zirconium metal shall conform to the requirements for chemical composition specified.
SCOPE
1.1 This specification covers one grade of virgin zirconium metal commonly designated as sponge because of its porous, sponge-like texture, but it may also take other forms such as chunklets, suitable for use in nuclear applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers vacuum-melted zirconium and zirconium alloy ingots for nuclear application. Materials covered shall be produced by multiple vacuum arc melting, or electron beam melting, or other melting processes conventionally used for reactive metals. Unless otherwise specified, ingots shall be conditioned by machining or grinding or both to remove surface and subsurface defects detrimental to subsequent fabrication. The ingot shall conform to the chemical composition requirements prescribed. The ingots shall be analyzed for the alloying and impurity elements prescribed. Ingots shall be inspected ultrasonically using the prescribed methods. The test shall be conducted in accordance with practice E 114.
SIGNIFICANCE AND USE
10.1 For purposes of determining compliance with the specified limits for requirements of the properties listed in Table 1 and Table 2, an observed value or a calculated value shall be rounded as indicated in accordance with the rounding method of Practice E29.
SCOPE
1.1 This specification covers vacuum-melted zirconium and zirconium alloy ingots for nuclear application.  
1.2 The values stated in either inch-pound units or SI units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers fittings, factory made from three grades of zirconium and zirconium alloys. The term welding fittings applies to butt-welding parts such as 45 and 90° elbows, 180° returns, caps, tees, reducers, lap-joint stub ends, and other types. The fittings are furnished in three grades as follows: Grade R60702 or PZ 2 which is unalloyed zirconium, Grade R60704 or PZ4 which is zirconium-tin, and Grade R60705 or PZ5 which is zirconium-niobium. Forging, forming, or shaping operations may be performed by hammering, pressing, piercing, extruding, upsetting, rolling, bending, fusion welding, machining, or by a combination of these operations. The forming procedure shall be so applied that it will not produce injurious defects in the fittings. Filler metal, when used, shall be the same grade as the base metal. The material shall conform to the requirements as to chemical composition and tensile properties specified.
SCOPE
1.1 This specification covers fittings, factory made from three grades of zirconium and zirconium alloys. The term welding fittings applies to butt-welding parts such as 45 and 90° elbows, 180° returns, caps, tees, reducers, lap-joint stub ends, and other types.  
1.2 The values stated in either inch-pound units or SI units are to be regarded separately as the standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers seamless and welded zirconium and zirconium alloy pipe. The pipe is furnished in three grades as follows; grade R60702- unalloyed zirconium, grade R60704- zirconium-tin alloy, and grade R60705- zirconium-niobium alloy. Seamless pipe shall be made from any seamless method that will yield a product meeting the requirements prescribed. Pipe containing welded seams or other joints made by welding shall comply with the given provisions. The pipe shall be furnished in the annealed or stress-relieved condition. The material shall conform to the requirements as to chemical composition prescribed. The material, as represented by the test specimens, shall conform to the tensile properties prescribed.
SCOPE
1.1 This specification2 covers three grades of seamless and welded zirconium pipe.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test methods portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers two grades (Grade R60702 and Grade R60703) of zirconium metal commonly designated as sponge or chunklets, but may also take other forms. This specification does not include crystal bar zirconium. This sponge is used in non-nuclear applications. Zirconium metal is usually prepared by reduction of zirconium tetrachloride, and it gets its physical characteristics from the processes involved in production. These characteristics may be expected to vary greatly with manufacturing methods. This specification, however, is not limited to metal prepared by reduction of tetrachloride or to material of any specific physical form. Only virgin zirconium metal, in identified, uniform, well-mixed blends, shall be supplied under this specification. The material shall conform to the chemical composition requirements for zirconium, hafnium, iron, chromium, hydrogen, nitrogen, carbon, and oxygen. The material shall be subjected to a number of chemical tests as required in this specification.
SCOPE
1.1 This specification covers two grades of zirconium metal commonly designated as sponge or chunklets, but may also take other forms. This specification does not include crystal bar zirconium. This sponge is used in non-nuclear applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers three grades of zirconium and zirconium alloy forgings. The forgings shall be formed with conventional forging equipment normally found in primary ferrous and nonferrous metal plants. The forgings are furnished in three grades as Grade R60702, Grade R60702, and Grade R60705. Forgings shall be furnished in the annealed conditions. The material shall conform to the requirements as to chemical composition and tensile properties prescribed. Two tension tests shall be made from each lot. Two chemistry tests for hydrogen and nitrogen content shall be made from each lot of finished product. If the results of any tests of any lot do not conform to the requirements specified, retests shall be made on additional forgings of double the original number of the same lot, each of which shall conform to the requirements specified.
SCOPE
1.1 This specification2 covers three grades of zirconium and zirconium alloy forgings (see 4.1).  
1.2 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.  
1.3 The following safety hazards caveat pertains only to the test method portion, Section 12, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is primarily used as an acceptance test for products of zirconium, hafnium, and their alloys. This standard has been widely used in the development of new alloys, heat treating practices, and for evaluation of welding techniques.  
5.2 Specimens are normally tested after careful etching and rinsing. Specimens with as-manufactured surfaces may also be tested without further surface removal.  
5.3 When tubing with a second material clad on the inner surface is to be tested, the inner cladding shall be removed prior to the test.
SCOPE
1.1 This test method covers (1) the determination of mass gain, and (2) the surface inspection of products of zirconium, hafnium, and their alloys when corrosion tested in water at 680°F [360°C] or in steam at 750°F [400°C].  
1.2 This test method is to be utilized in its entirety to the extent specified herein as a product acceptance test.  
1.3 This test method may be used on wrought products, castings, powder metallurgy products, and weld metals.  
1.4 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers three grades of zirconium and zirconium alloy bar and wire as grade R60702, unalloyed zirconium; grade R60704, zirconium-tin; and grade R60705, zirconium-niobium. The chemical composition; and mechanical properties requirements, such as tensile strength, yield strength, and elongation; are detailed.
SCOPE
1.1 This specification2 covers three grades of zirconium and zirconium alloy bar and wire.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test methods portions of this specification.This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the standard requirements for two grades of wrought hafnium and hafnium alloy strip, sheet, and plate: Grade R1 for nuclear applications and Grade R3 for commercial applications. The materials shall be made from ingots that are produced in a furnace by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of these three methods, or other melting process conventionally used for reactive metals. The various mill products shall be formed with the conventional extrusion, forging, or rolling equipment normally found in primary ferrous and nonferrous plants. The sheet, strip, and plate shall either be hot-rolled or cold-rolled and shall be supplied in the recrystallized annealed condition. Grades R1 and R3 metal shall conform to the chemical composition requirements for aluminum, carbon, chromium, copper, hydrogen, iron, molybdenum, nickel, niobium, nitrogen, oxygen, silicon, tantalum, tin, titanium, tungsten, uranium, vanadium, zirconium, and hafnium as shall be determined by chemical analysis. Mechanical properties, which shall be determined by tension tests both in longitudinal and transverse direction, shall meet the prescribed tensile strength, yield strength, and elongation requirements. Corrosion testing in water shall also be performed to determine the corrosion resistance of the materials.
SCOPE
1.1 This specification covers two grades of wrought hafnium and hafnium alloy strip, sheet, and plate as follows:  
1.1.1 Grade R1 for nuclear applications, and  
1.1.2 Grade R3 for commercial applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the three grades of zirconium and zirconium alloy seamless and welded tubes. The tubes are furnished in three grades as Grade R60702 which is an unalloyed zirconium, Grade R60704 which is zirconium-tin alloy, and Grade R60705 which is zirconium-niobium alloy. Seamless tube shall be made by any seamless method. Welded tube shall be made from sheet or strip by an automatic arc-welding process or other method of welding. Filler metal shall not be used. The material shall conform to the required chemical compostion for zirconium, hafnium, iron, chromium, tin, hydrogen, nitrogen, carbon, niobium, and oxygen. The materials shall conform to the required tensile properties such as tensile strength, yield strength, and elongation.
SCOPE
1.1 This specification2 covers two grades of zirconium and zirconium alloy seamless and welded tubes.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.  
1.3 The following precautionary caveat pertains only to the test methods portion of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers zirconium and zirconium-alloy castings for general corrosion-resistant and industrial applications. Material for this specification shall be melted by conventional processes used for reactive metals. Typical methods include the consumable electrode and inductoslag melting processes. The material shall conform to the required chemical composition for zirconium, hafnium, iron, chromium, hydrogen, nitrogen, carbon, oxygen, phosphorus, tin, and niobium. Product analysis and heat treatment shall be performed on the material, and shall conform within the specified check analysis tolerances.
SCOPE
1.1 This specification covers zirconium and zirconium-alloy castings for general corrosion-resistant and industrial applications.  
1.2 The values stated in either inch-pound units or SI units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system shall be used independently of each other. Combining values from the two systems may result in nonconformance with this specification.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers UNS R60001, R60802, R60804, and R60901 wrought zirconium and zirconium alloy bars, rods, and wires. All material grades covered should conform to the required chemical composition requirements. Elements that are intentionally added to the melt should be identified, analyzed and reported in the chemical analysis. The zirconium and zirconium alloys should be made from ingots produced by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of the three methods, or other melting processes conventionally used for reactive metals. All processes should be performed in furnaces specifically for reactive metals. Mill products included in this specification should be formed with conventional extrusion, forging, or rolling equipment that is used in primary ferrous and nonferrous plants. The cold worked and annealed materials should be in fully annealed condition unless otherwise specified. Hot worked shapes should be furnished in not descaled, mechanically descaled, or mechanically descaled and pickled finish, while cold-worked shapes should be furnished in cold-worked, ground, or pickled finish.
SCOPE
1.1 This specification covers four grades of wrought zirconium and zirconium alloy bars, rod, and wire as follows:  
1.1.1 R60001—Unalloyed grade,  
1.1.2 R60802—Zirconium-Tin alloy (Zircaloy 2),  
1.1.3 R60804—Zirconium-Tin alloy (Zircaloy 4), and  
1.1.4 R60901—Zirconium-Niobium alloy.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers seamless wrought zirconium-alloy tubes for nuclear reactor fuel cladding application. Two grades of reactor grade zirconium alloys are described. Tubes covered by this specification shall be made from ingots produced by multiple vacuum arc or electron beam melting in furnaces of a type conventionally used for reactive materials. The tubes shall conform to the requirements for chemical composition prescribed. Recrsytallisation annealed tubes shall conform to the requirements for mechanical properties at room temperature prescribed. The tension test shall be conducted. Yield strength and tension properties shall be determined. Burst testing, when specified, shall be performed at room temperature on finished tubing.
SCOPE
1.1 This specification covers seamless wrought zirconium-alloy tubes for nuclear fuel cladding application, in the outside diameter (OD) size range of 0.200 in. (5.1 mm) to 0.650 in. (16.5 mm) and wall thickness range of 0.010 in. (0.25 mm) to 0.035 in. (0.89 mm).  
1.2 Two grades of reactor grade zirconium alloys are described.  
1.2.1 The present UNS numbers designated for the two grades are given in Table 1.  
1.3 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.4 The following precautionary caveat pertains only to the test method portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the six grades of zirconium and zirconium alloy ingots: Grade R60700, Grade R60702, Grade R60703, Grade R60704, Grade R60705, and Grade R60706. These materials shall be manufactured by electron beam, vacuum, or inert atmosphere melting in furnaces. The material shall form to the required chemical composition of zirconium, hafnium, iron, chromium, tin, hydrogen, nitrogen, carbon, niobium, and oxygen. Check analysis shall be performed. The following test methods shall be done: ultrasonic test and chemical test.
SCOPE
1.1 This specification covers six grades of zirconium ingots.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 The following precautionary caveat pertains only to the test method portion, Section 10, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers five grades of zirconium strip, sheet, and plate. These are low oxygen zirconium (Grade R60700), unalloyed zirconium (Grade R60702), zirconium-tin (Grade R60704), zirconium-niobium (Grade R60705), and zirconium-niobium (Grade R60706). The materials shall be made from ingots that are produced by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of these three methods or other melting processes conventionally used for reactive metals. All processes to be done in furnaces usually used for reactive metals. The various mill products covered by this specification are formed with the conventional extrusion, forging, or rolling equipment normally found in primary ferrous and nonferrous plants. The strip, sheet, and plate shall be supplied in the recrystallized annealed condition unless otherwise specified in the purchase order. The materials shall be subjected to chemical analysis and tensile strength, yield strength, elongation, bend, and flatness tests.
SCOPE
1.1 This specification2 covers five grades of zirconium strip, sheet, and plate.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification:  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers hot- and cold-rolled zirconium and zirconium alloy sheet, strip, and plate.
SCOPE
1.1 This specification covers hot- and cold-rolled zirconium and zirconium alloy sheet, strip, and plate.  
1.2 One unalloyed and three alloys for use in nuclear applications are described.  
1.3 The products covered in this specification include the following forms and sizes:  
1.3.1 Sheet, 24 in. [600 mm] or more in width; under 0.187 in. [4.8 mm) in thickness,  
1.3.2 Strip, less than 24 in. [600 mm] in width; under 0.187 in. [4.8 mm] in thickness, and  
1.3.3 Plate, over 10 in. [250 mm] in width; 0.187 in. [4.8 mm] and over in thickness.
Note 1: Material over 0.187 in. [4.8 mm] in thickness and less than 10 in. [250 mm] wide is covered as bar in Specification B351/B351M.  
1.4 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers the standard requirements for wrought zirconium and zirconium alloy seamless and welded tubes for nuclear applications except for nuclear fuel cladding. Five grades of reactor grade zirconium and zirconium alloys with R60001, R60802, R60804, R60901, and R60904 UNS number designations are described. Material shall be made from ingots produced by vacuum arc melting, electron beam melting, or other melting process to be carried out in furnaces conventionally used for reactive metals. Seamless tubes may be made by billet extrusion with subsequent cold working, by drawing, swaging, or rocking, with intermediate annealing. Welded tubing shall be made from flat-rolled products by an automatic or semiautomatic welding process with no addition of filler metal and shall be cold reduced by drawing, swaging, or rocking. The products shall be in the recrystallized or cold-worked and stress-relieved conditions and shall be furnished by as-cold reducing, pickling, grounding, polishing, or end-saw cutting, machining, or shearing. Chemical and product analysis shall be performed on the materials which shall meet the chemical composition requirements for tin, iron, chromium, nickel, niobium, oxygen, and other impurity elements. The tensile properties shall be determined by a tensile test method and shall conform to the tensile strength, yield strength, and elongation limits. Steam and water corrosion tests and hydrostatic test shall be conducted to determine the acceptance criteria for corrosion and internal hydrostatic pressure, respectively. Burst properties, contractile strain ratio, grain size, and hydride orientation of the finished tubing shall also be determined.
SIGNIFICANCE AND USE
16.1 For the purpose of determining compliance with the specified limits of property requirements, an observed value or a calculated value shall be rounded in accordance with the rounding method of Practice E29.    
Test  
Rounded Units for Observed
or Calculated Value  
Chemical composition, tolerance
(when expressed in decimals)  
nearest unit in the last right hand place of figures of the specified limit  
Tensile strength and yield strength  
nearest 1000 psi (10 MPa)  
Elongation  
nearest 1 %
SCOPE
1.1 This specification covers seamless and welded wrought zirconium and zirconium-alloy tubes for nuclear application. Nuclear fuel cladding is covered in Specification B811.  
1.2 Five grades of reactor grade zirconium and zirconium alloys suitable for nuclear application are described.  
1.2.1 The present UNS numbers designated for the five grades are given in Table 1.  
1.3 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.4  The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This specification covers vacuum-melted zirconium and zirconium alloy ingots for nuclear application. Materials covered shall be produced by multiple vacuum arc melting, or electron beam melting, or other melting processes conventionally used for reactive metals. Unless otherwise specified, ingots shall be conditioned by machining or grinding or both to remove surface and subsurface defects detrimental to subsequent fabrication. The ingot shall conform to the chemical composition requirements prescribed. The ingots shall be analyzed for the alloying and impurity elements prescribed. Ingots shall be inspected ultrasonically using the prescribed methods. The test shall be conducted in accordance with practice E 114.
SIGNIFICANCE AND USE
10.1 For purposes of determining compliance with the specified limits for requirements of the properties listed in Table 1 and Table 2, an observed value or a calculated value shall be rounded as indicated in accordance with the rounding method of Practice E29.
SCOPE
1.1 This specification covers vacuum-melted zirconium and zirconium alloy ingots for nuclear application.  
1.2 The values stated in either inch-pound units or SI units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers hot- and cold-rolled zirconium and zirconium alloy sheet, strip, and plate.
SCOPE
1.1 This specification covers hot- and cold-rolled zirconium and zirconium alloy sheet, strip, and plate.  
1.2 One unalloyed and three alloys for use in nuclear applications are described.  
1.3 The products covered in this specification include the following forms and sizes:  
1.3.1 Sheet, 24 in. [600 mm] or more in width; under 0.187 in. [4.8 mm) in thickness,  
1.3.2 Strip, less than 24 in. [600 mm] in width; under 0.187 in. [4.8 mm] in thickness, and  
1.3.3 Plate, over 10 in. [250 mm] in width; 0.187 in. [4.8 mm] and over in thickness.
Note 1: Material over 0.187 in. [4.8 mm] in thickness and less than 10 in. [250 mm] wide is covered as bar in Specification B351/B351M.  
1.4 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers vacuum-melted zirconium and zirconium alloy ingots for nuclear application. Materials covered shall be produced by multiple vacuum arc melting, or electron beam melting, or other melting processes conventionally used for reactive metals. Unless otherwise specified, ingots shall be conditioned by machining or grinding or both to remove surface and subsurface defects detrimental to subsequent fabrication. The ingot shall conform to the chemical composition requirements prescribed. The ingots shall be analyzed for the alloying and impurity elements prescribed. Ingots shall be inspected ultrasonically using the prescribed methods. The test shall be conducted in accordance with practice E 114.
SIGNIFICANCE AND USE
10.1 For purposes of determining compliance with the specified limits for requirements of the properties listed in Table 1 and Table 2, an observed value or a calculated value shall be rounded as indicated in accordance with the rounding method of Practice E29.
SCOPE
1.1 This specification covers vacuum-melted zirconium and zirconium alloy ingots for nuclear application.  
1.2 The values stated in either inch-pound units or SI units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers seamless and welded zirconium and zirconium alloy pipe. The pipe is furnished in three grades as follows; grade R60702- unalloyed zirconium, grade R60704- zirconium-tin alloy, and grade R60705- zirconium-niobium alloy. Seamless pipe shall be made from any seamless method that will yield a product meeting the requirements prescribed. Pipe containing welded seams or other joints made by welding shall comply with the given provisions. The pipe shall be furnished in the annealed or stress-relieved condition. The material shall conform to the requirements as to chemical composition prescribed. The material, as represented by the test specimens, shall conform to the tensile properties prescribed.
SCOPE
1.1 This specification2 covers three grades of seamless and welded zirconium pipe.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test methods portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers one grade of virgin zirconium metal commonly designated as sponge because of its porous, sponge-like texture, but it may also take other forms such as chunklets. The one grade described is designated as Reactor Grade R60001, suitable for use in nuclear applications. The main characteristic of the reactor grade is its low nuclear cross section as achieved by removal of hafnium. Zirconium metal is usually prepared by reduction of zirconium tetrachloride, and gets its physical characteristics from the processes involved in production. These characteristics may be expected to vary greatly with manufacturing methods. Only virgin zirconium metal, in identified, uniform, well-mixed blends, shall be used. The zirconium metal shall conform to the requirements for chemical composition specified.
SCOPE
1.1 This specification covers one grade of virgin zirconium metal commonly designated as sponge because of its porous, sponge-like texture, but it may also take other forms such as chunklets, suitable for use in nuclear applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers fittings, factory made from three grades of zirconium and zirconium alloys. The term welding fittings applies to butt-welding parts such as 45 and 90° elbows, 180° returns, caps, tees, reducers, lap-joint stub ends, and other types. The fittings are furnished in three grades as follows: Grade R60702 or PZ 2 which is unalloyed zirconium, Grade R60704 or PZ4 which is zirconium-tin, and Grade R60705 or PZ5 which is zirconium-niobium. Forging, forming, or shaping operations may be performed by hammering, pressing, piercing, extruding, upsetting, rolling, bending, fusion welding, machining, or by a combination of these operations. The forming procedure shall be so applied that it will not produce injurious defects in the fittings. Filler metal, when used, shall be the same grade as the base metal. The material shall conform to the requirements as to chemical composition and tensile properties specified.
SCOPE
1.1 This specification covers fittings, factory made from three grades of zirconium and zirconium alloys. The term welding fittings applies to butt-welding parts such as 45 and 90° elbows, 180° returns, caps, tees, reducers, lap-joint stub ends, and other types.  
1.2 The values stated in either inch-pound units or SI units are to be regarded separately as the standard. Within the text, the SI units are shown in brackets. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This practice covers a cleaning and de-scaling procedure useful to producers, users, and fabricators of zirconium and zirconium alloys for the removal of ordinary shop soils, oxides, and scales resulting from heat treatment operations and foreign substances present as surface contaminants. Grease, oil, and lubricants employed in machining, forming, and fabricating operations on zirconium and zirconium alloys should be removed by employing one of the methods or a combination of methods: alkaline or emulsion soak-type cleaners, ultrasonic cleaning, acetone, citrus based cleaners, or safety solvent immersion washing or vapor degreasing, or electrolytic alkaline cleaning system. Mechanical de-scaling methods such as sandblasting, shot blasting, and vapor blasting may be used to remove hot work scales and lubricants from zirconium surfaces if followed by thorough conditioning and cleaning. Aluminum oxide, silicon carbide, silica sand, zircon sand, and steel grit are acceptable media for mechanical de-scaling. Recommended post treatment of shot or abrasive blasted zirconium surfaces may include acid pickling to ensure complete removal of metallic iron, oxide, scale, and other surface contaminants. Visual inspection of material cleaned in accordance with this practice should show no evidence of paint, oil, grease, glass, graphite, lubricant, scale, abrasive, iron, or other forms of contamination.
SCOPE
1.1 This practice covers a cleaning and descaling procedure useful to producers, users, and fabricators of zirconium and zirconium alloys for the removal of ordinary shop soils, oxides, and scales resulting from heat treatment operations and foreign substances present as surface contaminants.  
1.2 It is not intended that these procedures become mandatory for removal of any of the indicated soils but rather serve as a guide when zirconium and zirconium alloys are being processed in the wrought, cast, or fabricated form.  
1.3 It is the intent that these soils be removed prior to chemical milling, joining, plating, welding, fabrication, and in any situation where foreign substances interfere with the corrosion resistance, stability, and quality of the finished product.  
1.4 Unless a single unit is used, for example, solution concentrations in g/l, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Sections 3 and 7.

ABSTRACT
This specification covers hot-, cold-, or both hot- and cold-rolled hafnium rods and wires in either one of two grades. All grades should be in the recrystallization annealed condition unless specified otherwise. The materials should be made from ingots produced by vacuum melting in an electron beam or consumable arc furnaces, or both, of a type conventionally used for reactive metals. Samples for chemical composition tests should be taken from the top, middle, and bottom of the ingots. The requirements for mechanical properties do not apply to wires. Corrosion tests shall be done in water. All rods should be furnished in mechanically descaled and pickled, centerless ground and pickled, or centerless ground, pickled, and oxidized surface finish, while wires should be furnished in either conditioned and pickled or conditioned, pickled, and oxidized surface finish.
SIGNIFICANCE AND USE
15.1 For the purpose of determining compliance with the specified limits for requirements of the properties listed in the following table, an observed value or a calculated value shall be rounded as indicated in accordance with the rounding methods of Practice E29.    
Property  
Rounded Unit for Observed
or Calculated Value  
Chemical composition, and tolerances (when expressed as decimals)  
nearest unit in the last right-hand place of figures of the specified limit  
Tensile strength and yield strength  
nearest 1000 psi (10 MPa)  
Elongation  
nearest 1 %
SCOPE
1.1 This specification covers hot- or cold-worked hafnium rod and wire.  
1.2 This specification contains two material grades, one specifically for nuclear applications (Grade R1) and one for commercial alloying applications (Grade R3).  
1.3 The products covered include the following:  
1.3.1 Rod 3/8 to 1 in. (9.5 to 25 mm) in diameter.  
1.3.2 Wire less than 3/8 in. (9.5 mm) in diameter.  
1.4 Unless a single unit is used, for example, corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers two grades (Grade R60702 and Grade R60703) of zirconium metal commonly designated as sponge or chunklets, but may also take other forms. This specification does not include crystal bar zirconium. This sponge is used in non-nuclear applications. Zirconium metal is usually prepared by reduction of zirconium tetrachloride, and it gets its physical characteristics from the processes involved in production. These characteristics may be expected to vary greatly with manufacturing methods. This specification, however, is not limited to metal prepared by reduction of tetrachloride or to material of any specific physical form. Only virgin zirconium metal, in identified, uniform, well-mixed blends, shall be supplied under this specification. The material shall conform to the chemical composition requirements for zirconium, hafnium, iron, chromium, hydrogen, nitrogen, carbon, and oxygen. The material shall be subjected to a number of chemical tests as required in this specification.
SCOPE
1.1 This specification covers two grades of zirconium metal commonly designated as sponge or chunklets, but may also take other forms. This specification does not include crystal bar zirconium. This sponge is used in non-nuclear applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers three grades of zirconium and zirconium alloy forgings. The forgings shall be formed with conventional forging equipment normally found in primary ferrous and nonferrous metal plants. The forgings are furnished in three grades as Grade R60702, Grade R60702, and Grade R60705. Forgings shall be furnished in the annealed conditions. The material shall conform to the requirements as to chemical composition and tensile properties prescribed. Two tension tests shall be made from each lot. Two chemistry tests for hydrogen and nitrogen content shall be made from each lot of finished product. If the results of any tests of any lot do not conform to the requirements specified, retests shall be made on additional forgings of double the original number of the same lot, each of which shall conform to the requirements specified.
SCOPE
1.1 This specification2 covers three grades of zirconium and zirconium alloy forgings (see 4.1).  
1.2 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.  
1.3 The following safety hazards caveat pertains only to the test method portion, Section 12, of this specification: This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers UNS R60001, R60802, R60804, and R60901 wrought zirconium and zirconium alloy bars, rods, and wires. All material grades covered should conform to the required chemical composition requirements. Elements that are intentionally added to the melt should be identified, analyzed and reported in the chemical analysis. The zirconium and zirconium alloys should be made from ingots produced by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of the three methods, or other melting processes conventionally used for reactive metals. All processes should be performed in furnaces specifically for reactive metals. Mill products included in this specification should be formed with conventional extrusion, forging, or rolling equipment that is used in primary ferrous and nonferrous plants. The cold worked and annealed materials should be in fully annealed condition unless otherwise specified. Hot worked shapes should be furnished in not descaled, mechanically descaled, or mechanically descaled and pickled finish, while cold-worked shapes should be furnished in cold-worked, ground, or pickled finish.
SCOPE
1.1 This specification covers four grades of wrought zirconium and zirconium alloy bars, rod, and wire as follows:  
1.1.1 R60001—Unalloyed grade,  
1.1.2 R60802—Zirconium-Tin alloy (Zircaloy 2),  
1.1.3 R60804—Zirconium-Tin alloy (Zircaloy 4), and  
1.1.4 R60901—Zirconium-Niobium alloy.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers seamless wrought zirconium-alloy tubes for nuclear reactor fuel cladding application. Two grades of reactor grade zirconium alloys are described. Tubes covered by this specification shall be made from ingots produced by multiple vacuum arc or electron beam melting in furnaces of a type conventionally used for reactive materials. The tubes shall conform to the requirements for chemical composition prescribed. Recrsytallisation annealed tubes shall conform to the requirements for mechanical properties at room temperature prescribed. The tension test shall be conducted. Yield strength and tension properties shall be determined. Burst testing, when specified, shall be performed at room temperature on finished tubing.
SCOPE
1.1 This specification covers seamless wrought zirconium-alloy tubes for nuclear fuel cladding application, in the outside diameter (OD) size range of 0.200 in. (5.1 mm) to 0.650 in. (16.5 mm) and wall thickness range of 0.010 in. (0.25 mm) to 0.035 in. (0.89 mm).  
1.2 Two grades of reactor grade zirconium alloys are described.  
1.2.1 The present UNS numbers designated for the two grades are given in Table 1.TABLE 1 ASTM and UNS Number Designation for Reactor Grade Zirconium Alloys    
Grade  
UNS Number  
Zirconium-tin alloy  
R60802  
Zirconium-tin alloy  
R60804
1.3 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.4 The following precautionary caveat pertains only to the test method portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers seamless wrought zirconium-alloy tubes for nuclear reactor fuel cladding application. Two grades of reactor grade zirconium alloys are described. Tubes covered by this specification shall be made from ingots produced by multiple vacuum arc or electron beam melting in furnaces of a type conventionally used for reactive materials. The tubes shall conform to the requirements for chemical composition prescribed. Recrsytallisation annealed tubes shall conform to the requirements for mechanical properties at room temperature prescribed. The tension test shall be conducted. Yield strength and tension properties shall be determined. Burst testing, when specified, shall be performed at room temperature on finished tubing.
SCOPE
1.1 This specification covers seamless wrought zirconium-alloy tubes for nuclear fuel cladding application, in the outside diameter (OD) size range of 0.200 in. (5.1 mm) to 0.650 in. (16.5 mm) and wall thickness range of 0.010 in. (0.25 mm) to 0.035 in. (0.89 mm).  
1.2 Two grades of reactor grade zirconium alloys are described.  
1.2.1 The present UNS numbers designated for the two grades are given in Table 1.  
1.3 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.4 The following precautionary caveat pertains only to the test method portions of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers the standard requirements for wrought zirconium and zirconium alloy seamless and welded tubes for nuclear applications except for nuclear fuel cladding. Five grades of reactor grade zirconium and zirconium alloys with R60001, R60802, R60804, R60901, and R60904 UNS number designations are described. Material shall be made from ingots produced by vacuum arc melting, electron beam melting, or other melting process to be carried out in furnaces conventionally used for reactive metals. Seamless tubes may be made by billet extrusion with subsequent cold working, by drawing, swaging, or rocking, with intermediate annealing. Welded tubing shall be made from flat-rolled products by an automatic or semiautomatic welding process with no addition of filler metal and shall be cold reduced by drawing, swaging, or rocking. The products shall be in the recrystallized or cold-worked and stress-relieved conditions and shall be furnished by as-cold reducing, pickling, grounding, polishing, or end-saw cutting, machining, or shearing. Chemical and product analysis shall be performed on the materials which shall meet the chemical composition requirements for tin, iron, chromium, nickel, niobium, oxygen, and other impurity elements. The tensile properties shall be determined by a tensile test method and shall conform to the tensile strength, yield strength, and elongation limits. Steam and water corrosion tests and hydrostatic test shall be conducted to determine the acceptance criteria for corrosion and internal hydrostatic pressure, respectively. Burst properties, contractile strain ratio, grain size, and hydride orientation of the finished tubing shall also be determined.
SIGNIFICANCE AND USE
16.1 For the purpose of determining compliance with the specified limits of property requirements, an observed value or a calculated value shall be rounded in accordance with the rounding method of Practice E29.    
Test  
Rounded Units for Observed
or Calculated Value  
Chemical composition, tolerance
(when expressed in decimals)  
nearest unit in the last right hand place of figures of the specified limit  
Tensile strength and yield strength  
nearest 1000 psi (10 MPa)  
Elongation  
nearest 1 %
SCOPE
1.1 This specification covers seamless and welded wrought zirconium and zirconium-alloy tubes for nuclear application. Nuclear fuel cladding is covered in Specification B811.  
1.2 Five grades of reactor grade zirconium and zirconium alloys suitable for nuclear application are described.  
1.2.1 The present UNS numbers designated for the five grades are given in Table 1.TABLE 1 ASTM and UNS Number Designations for Reactor Grade Zirconium and Zirconium Alloys    
Grade  
UNS Number  
Reactor-grade zirconium  
R60001  
Zirconium-tin alloy  
R60802  
Zirconium-tin alloy  
R60804  
Zirconium-niobium alloy  
R60901  
Zirconium-niobium alloy  
R60904
1.3 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.4  The following precautionary caveat pertains only to the test method portions of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers the standard requirements for two grades of wrought hafnium and hafnium alloy strip, sheet, and plate: Grade R1 for nuclear applications and Grade R3 for commercial applications. The materials shall be made from ingots that are produced in a furnace by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of these three methods, or other melting process conventionally used for reactive metals. The various mill products shall be formed with the conventional extrusion, forging, or rolling equipment normally found in primary ferrous and nonferrous plants. The sheet, strip, and plate shall either be hot-rolled or cold-rolled and shall be supplied in the recrystallized annealed condition. Grades R1 and R3 metal shall conform to the chemical composition requirements for aluminum, carbon, chromium, copper, hydrogen, iron, molybdenum, nickel, niobium, nitrogen, oxygen, silicon, tantalum, tin, titanium, tungsten, uranium, vanadium, zirconium, and hafnium as shall be determined by chemical analysis. Mechanical properties, which shall be determined by tension tests both in longitudinal and transverse direction, shall meet the prescribed tensile strength, yield strength, and elongation requirements. Corrosion testing in water shall also be performed to determine the corrosion resistance of the materials.
SCOPE
1.1 This specification covers two grades of wrought hafnium and hafnium alloy strip, sheet, and plate as follows:  
1.1.1 Grade R1 for nuclear applications, and  
1.1.2 Grade R3 for commercial applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification.  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers the three grades of zirconium and zirconium alloy seamless and welded tubes. The tubes are furnished in three grades as Grade R60702 which is an unalloyed zirconium, Grade R60704 which is zirconium-tin alloy, and Grade R60705 which is zirconium-niobium alloy. Seamless tube shall be made by any seamless method. Welded tube shall be made from sheet or strip by an automatic arc-welding process or other method of welding. Filler metal shall not be used. The material shall conform to the required chemical compostion for zirconium, hafnium, iron, chromium, tin, hydrogen, nitrogen, carbon, niobium, and oxygen. The materials shall conform to the required tensile properties such as tensile strength, yield strength, and elongation.
SCOPE
1.1 This specification2 covers two grades of zirconium and zirconium alloy seamless and welded tubes.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test methods portion of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers the three grades of zirconium and zirconium alloy seamless and welded tubes. The tubes are furnished in three grades as Grade R60702 which is an unalloyed zirconium, Grade R60704 which is zirconium-tin alloy, and Grade R60705 which is zirconium-niobium alloy. Seamless tube shall be made by any seamless method. Welded tube shall be made from sheet or strip by an automatic arc-welding process or other method of welding. Filler metal shall not be used. The material shall conform to the required chemical compostion for zirconium, hafnium, iron, chromium, tin, hydrogen, nitrogen, carbon, niobium, and oxygen. The materials shall conform to the required tensile properties such as tensile strength, yield strength, and elongation.
SCOPE
1.1 This specification covers three grades of zirconium and zirconium alloy seamless and welded tubes.
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore, each system must be used independently of the other. SI values cannot be mixed with inch-pound values.
1.3 The following precautionary caveat pertains only to the test methods portion of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers five grades of zirconium strip, sheet, and plate. These are low oxygen zirconium (Grade R60700), unalloyed zirconium (Grade R60702), zirconium-tin (Grade R60704), zirconium-niobium (Grade R60705), and zirconium-niobium (Grade R60706). The materials shall be made from ingots that are produced by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of these three methods or other melting processes conventionally used for reactive metals. All processes to be done in furnaces usually used for reactive metals. The various mill products covered by this specification are formed with the conventional extrusion, forging, or rolling equipment normally found in primary ferrous and nonferrous plants. The strip, sheet, and plate shall be supplied in the recrystallized annealed condition unless otherwise specified in the purchase order. The materials shall be subjected to chemical analysis and tensile strength, yield strength, elongation, bend, and flatness tests.
SCOPE
1.1 This specification covers five grades of zirconium strip, sheet, and plate.
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.
1.3 The following precautionary caveat pertains only to the test method portions of this specification:  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ABSTRACT
This specification covers three grades of zirconium and zirconium alloy bar and wire as grade R60702, unalloyed zirconium; grade R60704, zirconium-tin; and grade R60705, zirconium-niobium. The chemical composition; and mechanical properties requirements, such as tensile strength, yield strength, and elongation; are detailed.
SCOPE
1.1 This specification covers three grades of zirconium and zirconium alloy bar and wire.
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.
1.3 The following precautionary caveat pertains only to the test methods portions of this specification.  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 This test method is primarily used as an acceptance test for products of zirconium, hafnium, and their alloys. This standard has been widely used in the development of new alloys, heat treating practices, and for evaluation of welding techniques.  
5.2 Specimens are normally tested after careful etching and rinsing. Specimens with as-manufactured surfaces may also be tested without further surface removal.  
5.3 When tubing with a second material clad on the inner surface is to be tested, the inner cladding shall be removed prior to the test.
SCOPE
1.1 This test method covers (1) the determination of mass gain, and (2) the surface inspection of products of zirconium, hafnium, and their alloys when corrosion tested in water at 680°F [360°C] or in steam at 750°F [400°C].  
1.2 This test method is to be utilized in its entirety to the extent specified herein as a product acceptance test.  
1.3 This test method may be used on wrought products, castings, powder metallurgy products, and weld metals.  
1.4 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Section 9.

SIGNIFICANCE AND USE
This test method is primarily used as an acceptance test for products of zirconium, hafnium, and their alloys. This standard has been widely used in the development of new alloys, heat treating practices, and for evaluation of welding techniques.
Specimens are normally tested after careful etching and rinsing. Specimens with as-manufactured surfaces may also be tested without further surface removal.
When tubing with a second material clad on the inner surface is to be tested, the inner cladding shall be removed prior to the test.
SCOPE
1.1 This test method covers (1) the determination of mass gain, and (2) the surface inspection of products of zirconium, hafnium, and their alloys when corrosion tested in water at 680°F [360°C] or in steam at 750°F [400°C].
1.2 This test method is to be utilized in its entirety to the extent specified herein as a product acceptance test.
1.3 This test method may be used on wrought products, castings, powder metallurgy products, and weld metals.
1.4 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Section 9.