D01.24 - Physical Properties of Liquid Paints & Paint Materials

SIGNIFICANCE AND USE
5.1 By following this test method, the particle size, particle size distribution and particle shape of particulates in liquid paint and pigment dispersions can be measured.  
5.2 Particle size, particle size distribution and particle shape have a great effect on the color, opacity and gloss of paints. Reproducing these characteristics is critical to the quality and performance of the paint produced.  
5.3 The dynamic imaging instrument is useful during manufacturing to detect oversize particles as well as the required size distribution of particles in order to provide quality and consistency from batch to batch.
SCOPE
1.1 This test method covers the determination of particle size distribution of liquid paints and pigmented liquid coatings by Dynamic Image Analysis. This method includes the reporting of particles ≥1 µm in size and up to 300 µm in size.
Note 1: Shape is used to classify particles, droplets and bubbles and is not a reporting requirement.
Note 2: The term paint(s) as used in this document includes liquid paint and liquid pigmented coatings.  
1.1.1 Some paints may be too viscous to flow through the imaging instrument without dilution which may be used to help the paint flow as long as significant contamination is not introduced into the paint.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The viscosity value obtained by this test method gives information about the flow properties of the material under high-shear conditions similar to those encountered during application: brushing (see Test Method D4958), spraying, electrostatic disk, or roll coating.  
4.2 This test method is suitable for all paints and varnishes whether they are Newtonian in behavior or not. However, due to the narrow gap between the stationary and rotary parts of high-shear viscometers, this test method is more reproducible for paints having finer pigment dispersions as determined by Test Method D1210.
SCOPE
1.1 This test method covers the determination of the viscosity of paints, varnishes, and related products at a rate of shear of 12 000 s−1.  
1.2 Paints and varnishes that dry very rapidly may not give reproducible results with this test method. Measurements made at elevated temperatures may also give poor precision due to loss of volatiles and to drying.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method covers the procedures for determining the viscosity of transparent liquids by bubble time method. The transparent liquids should be free from crystalline or gel particles. Test apparatus include a constant-temperature bath, standard viscosity tubes, a series of standard viscosity tubes as reference standards, timing device, tube racks, and viscosity tube corks.
SCOPE
1.1 This test method covers the determination of the viscosity in bubble seconds by timing. The bubble seconds are approximately equal to stokes for most liquids.  
1.2 The test method is applicable to transparent liquids that are free from crystalline or gel particles.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Viscosity is a measure of the fluidity of a material. Viscosity data are useful in the determination of the ease of stirring, pumping, dip coating, or other flow-related properties of paints and related fluids.  
5.2 This type of cup is used to measure viscosity because it is easy to use, robust, and may be used in tanks, reservoirs, and reactors.  
5.3 There are other types of apparatus for measuring viscosity in the laboratory that provide better precision and bias, including the Ford viscosity cup (Test Method D1200), and the rotational viscometer (Test Methods D2196).  
5.4 Certain higher shear rate devices such as cone/plate viscometers (Test Method D4287) provide more information about sprayability, roll coatability, and other high-shear rate related properties of coatings.
SCOPE
1.1 This test method covers the determination of viscosity of paints, varnishes, lacquers, inks, and related liquid materials by dip-type viscosity cups. This test method is recommended for viscosity control work within one plant or laboratory and should be used to check compliance with specifications only when sufficient controls have been instituted to ensure adequate comparability of results.  
1.2 Viscosity cups are designed for testing of Newtonian and near-Newtonian liquids. If the test material is non-Newtonian, for example, shear-thinning or thixotropic, another method, such as Test Methods D2196, should be used. Under controlled conditions, comparisons of the viscosity of non-newtonian materials may be helpful, but viscosity determination methods using controlled shear rate or shear stress are preferred.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 High speed dispersion is a commonly used dispersion method in the coatings industry. For the purpose of this practice, “high speed” would normally be understood to be a range of RPM between 3 000 and 10 000. This practice provides a reference for its use, so that a producer and user can standardize on an incorporation technique. This will minimize differences in the millbase, and allow the interested parties to concentrate on the physical, chemical, or optical methods to be run.
SCOPE
1.1 This practice covers the dispersion of pigments using a laboratory size high-speed impeller mill. It is similar in technical content to ISO 8780-3.
Note 1: This practice is restricted to mill bases of moderately high viscosity due to either high vehicle concentration or high pigment concentration, or both, which can produce high shear force. It is not intended to provide a means of formulating either pilot plant or full-scale mill base compositions (scaling up the process from laboratory equipment to factory mills is not simple).  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 These tests are suitable for testing paints adjusted for compatibility with various electrostatic spray coating applications, and by their use, spray performance can be optimized.
SCOPE
1.1 These test methods cover the determination of specific resistance (resistivity) of liquid paints, solvents, and other fluids in the range of 0.6 to 2640 MΩ-cm.  
1.2 Test Method A describes a procedure for making resistance tests with a commonly used paint application test assembly (Fig. 1 and Fig. 2).
FIG. 1 Analog Paint Application Test Assembly  
FIG. 2 Diagram of Digital Application Test Assembly  
1.3 Test Method B describes a procedure for making resistance tests with a conductivity meter (Fig. 3).
FIG. 3 Conductivity Meter  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The oil absorption value obtained by this test method provides information about the vehicle demand of the pigment when it is used in a pigment paste. Oil absorption values can be used to characterize batches of a given pigment.  
4.2 This test method differs from Test Method D281 in that D281 requires a vigorous rubbing action whereas this test method involves only a gentle stirring and folding of the pigment. Because the end points are different, the values obtained from the two test methods generally differ.
SCOPE
1.1 This test method covers the determination of oil absorption of pigments by the Gardner-Coleman procedure.2  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is useful for the determination of package and application viscosities of a number of paints and other coatings and in the thinning of these materials, but is limited to Newtonian or near-Newtonian liquids.  
5.2 There are other types of apparatus for measuring viscosity in the laboratory that produce more accurate results.
SCOPE
1.1 This test method covers the determination of the viscosity of Newtonian or near-Newtonian paints, varnishes, lacquers, and related liquid materials with the Ford-type efflux viscosity cup. If the material is non-Newtonian, that is, shear-thinning or thixotropic, Test Method D2196 should be used.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 A significant feature of this practice is the ability to survey coating rheology over a broad range of shear rates with the same bench viscometers and test protocol that paint formulators and paint quality control (QC) analysts routinely use. By using this procedure, measurement of the shear rheology of a coating is possible without using an expensive laboratory rheometer, and performance predictions can be made based on those measurements.  
5.2 Low-Shear Viscosity (LSV)—The determination of low-shear viscosity in this practice can be used to predict the relative “in-can” performance of coatings for their ability to suspend pigment or prevent syneresis, or both. The LSV can also predict relative performance for leveling and sag resistance after application by roll, brush or spray. Fig. 1 shows the predictive low-shear viscosity relationships for several coatings properties.
FIG. 1 Low Shear Viscosity (LSV)  
5.3 Mid-Shear Viscosity (MSV)—The determination of MSV (coating consistency) in this practice is often the first viscosity obtained. This viscosity reflects the coatings resistance to flow on mixing, pouring, pumping, or hand stirring. Architectural coatings nearly always have a target specification for mid-shear viscosity, which is usually obtained by adjusting the level of thickener in the coating. Consequently, mid-shear viscosity is ideally a constant for a given series of coatings being tested to provide meaningful comparisons of low-shear and high-shear viscosity. With viscosities at the same KU value, MSV can also be used to obtain the relative Mid-Shear Thickener Efficiency (MSTE) of different thickeners in the same coating expressed as lb thickener/100 gal wet coating or g thickener/L wet coating.  
5.4 High-Shear Viscosity (HSV)—High-shear viscosity in this practice is a measure of the coatings resistance to flow on application by brush or roller, which is often referred to as brush-drag or rolling resistance respectively. This viscosity rela...
SCOPE
1.1 This practice describes a popular industry protocol for the rheological characterization of waterborne architectural coatings using three commonly used rotational bench viscometers. Each viscometer operates in a different shear rate regime for determination of coating viscosity at low shear rate, mid shear rate, and at high shear rate respectively as defined herein. General guidelines are provided for predicting some coating performance properties from the viscosity measurements made. With appropriate correlations and subsequent modification of the performance guidelines, this practice has potential for characterization of other types of aqueous and non-aqueous coatings.  
1.2 The values in common viscosity units (Krebs Units, KU and Poise, P) are to be regarded as standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test has been used to measure viscosities of automotive topcoats in place of No. 4 Ford cup measurements and has provided an equivalent ability to evaluate whether the paint meets specifications and is sprayable.  
4.2 The method could be considered as an alternative to No. 4 Ford cup and other efflux cup measurements for other products as well.  
4.3 The type of viscometer described in this method gives better temperature control than Ford and other efflux cups and is expected to give better precision.  
4.4 This test method is suitable for all paints and related materials whether they are Newtonian in behavior or not.
SCOPE
1.1 This test method covers the determination of the viscosity of paints and related products using a cone/plate viscometer at a shear rate of 500 s-1.  
1.2 Viscosity values obtained by this method may be used as an alternative to results from No. 4 Ford cup measurements. The values from this method do not replicate Ford cup results, but can be used for quality control, producer-user specifications and viscosity reduction in the same manner that Ford cups are used.  
1.3 If viscosity at a higher shear rate is needed, Test Method D4287, which describes viscosity measurement at 10 000 s-1 to 12 000 s-1 may be used.  
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are provided for information only and are not considered standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method provides values that are useful in specifying and controlling the consistency of paints, such as consumer or trade sales products.
SCOPE
1.1 This test method covers the measurement of Krebs Unit (KU) viscosity to evaluate the consistency of paints and related coatings using the Stormer-type viscometer.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 These test methods are applicable for measuring the rheological properties of varnishes and paints. In particular, the low to moderate shear rate measurements provide information related to sag resistance, leveling, etc.
SCOPE
1.1 These test methods cover the measurement of the viscosity of Newtonian and non-Newtonian liquids. These test methods are applicable to liquids having viscosities in the range from 5 × 10−4 Pa·s to 103 Pa·s (0.5 cP to 106 cP). The shear rate range is dependent upon the needle used and viscosity of the liquid and may vary from 10−4 s−1 to 103 s−1. With an extension bar and applied weight, a shear rate of 104 s–1 may be achieved.  
1.2 The yield stress of liquids having this property may also be determined.  
1.3 These test methods consist of determining liquid viscosities of Newtonian and non-Newtonian fluids (clear or opaque) by measuring the steady-state (constant) or terminal velocities of cylindrical needles as they fall through the test liquid under the influence of gravity. Yield stresses of non-Newtonian liquids may be measured using the same procedure.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 In making pigmented products, the pigment is usually dispersed in a portion of the vehicle in some sort of mill. At this stage, it is necessary to be able to judge if the pigment agglomerates have been sufficiently broken up so as not to interfere with the smoothness of the finished coating film. This test method describes a way of making this judgment.
SCOPE
1.1 This test method covers measurement of the degree of dispersion (commonly referred to as “fineness of grind”) of the pigment in a pigment-vehicle system such as liquid coatings and their intermediates. It may also be used to assess the inclusion of particulates by a cleanliness (or texture) rating.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Paints, if not formulated or processed properly may settle excessively. Paint that settles excessively is difficult to reincorporate into the paint system causing time delays or valuable pigment being left in the drum. This test method is an attempt to evaluate the degree of settling caused by the accelerated Test Method D1309. This very subjective method of evaluation in conjunction with the variables of Test Method D1309 raises questions as to the usefulness of the results for specification compliance.
SCOPE
1.1 This test method covers the determination of the degree of pigment suspension and ease of remixing a shelf-aged sample of paint to a homogeneous condition suitable for the intended use.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The oil absorption value obtained by this test method gives information about the vehicle demand of the pigment when it is used in a pigment paste. Oil absorption values can be used to characterize pigments or batches of a given pigment.  
4.2 This test method differs from Test Method D1483 in that D1483 involves only a gentle stirring and folding of the pigment, whereas this test method requires a thorough rubbing action. Because the end points are different, the values obtained from the two test methods generally differ.
SCOPE
1.1 This test method covers the determination of the oil absorption of pigments by the spatula rub-out technique.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 Physical constants of paints and coatings are required in all aspects of their formulation, manufacture and use. This practice demonstrates standard methods agreed upon for calculating formulation values for some of these physical constants. The calculations are the same for either metric or inch/pound units.  
4.2 These formula values may not be used to replace measured values required by government regulations unless specifically stated in the governing documents.  
4.3 Some regulations allow compliance determination using formulation data instead of analytical data. This formulation data may not yield the same results as the required analytical method, which could be performed on a sample from any production batch of the coating. In these cases, the user may wish to compare formulation data to analytical data and develop a factor that adjusts for variability of raw materials, variability of production batches, cure volatiles, and variability of the analytical methods.
SCOPE
1.1 This practice covers procedures commonly used in the paint industry to formulate paints and coating materials. It describes procedures for calculating formulation values for weight solids, volume solids, solvent content, volatile organic compound (VOC) content, hazardous air pollutant (HAP) content, and density of liquid paints and coatings. These values are calculated from basic formulation data. These calculations may be related to either as-supplied (unreduced) or as-applied (reduced) coating materials, including multicomponent types.  
1.2 These calculated, formulation-based values may or may not be acceptable for VOC regulatory purposes, depending on the specific wording of the applicable regulation. Some regulations require analysis of the coating. Some rules allow the use of formulation data, however, some adjustments may be needed to the values calculated in this practice before they are used for regulatory purposes (see 4.3).  
1.3 For purposes of this practice, it is assumed that volatile components evaporate and the materials that remain are identified as coating solids. For example, solvents are normally used to adjust viscosity for application and appearance of the coating. Other liquid materials, such as plasticizers, reactive diluents, etc., that are expected to be retained in the dried film to affect the final physical properties should be classified as part of the coating solids. Standards such as Test Methods D2369, D4758, D5403, and Guide D2832 may be used to determine volatile or nonvolatile content of specific components. For purposes of this practice it is assumed that the blended formulation behaves as an ideal solution with no volume change on mixing (see 6.2).  
1.4 Volatile by-products of cross-linking reactions (cure volatiles) are not considered in these calculations since the object of this practice is to define paint physical constants based on formulation information. Variations in raw materials, variations in the production processes, test methods, and test method accuracy are not taken into account in these calculations.  
1.5 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. However, they may be readily converted into SI units, if required by the user (for example, see Note 4).  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 These methods provide data that are useful in evaluating the effectiveness of surface active agents in reducing surface tension. In addition, surface tension data can predict interactions between liquids and solid surfaces or other liquids and can be used to establish wetting properties of paints, solvents, and other liquids.  
5.2 A number of laboratories have found the Wilhelmy plate to be easier to use, easier to clean and generally better for use with pigmented paints.
SCOPE
1.1 These test methods cover the determination of surface tension and interfacial tension of a variety of liquid materials, including but not restricted to paints, solvents, and solutions of surface-active agents, as defined in Terminology D459. Four methods are covered as follows:
Method A—Surface Tension by du Noüy ring;
Method B—Interfacial Tension by du Noüy ring;
Method C—Surface Tension by Wilhelmy plate; and
Method D—Interfacial Tension by Wilhelmy plate.  
1.2 Method A originally was written primarily to cover aqueous solutions of surface-active agents, but is also applicable to aqueous paints, nonaqueous solutions (including paints) and mixed solvent solutions.  
1.3 Method B is applicable to two-phase solutions. More than one solute component may be present, including solute components that are not in themselves surface-active.  
1.4 Method C is applicable to surface active liquids and, unlike du Noüy ring, no buoyancy corrections are needed and results are not affected by moderate viscosities (1-10 Pa-sec) of the liquid. It is the recommended method for use with paints and resin solutions.  
1.5 Method D is applicable to two-phase solutions and mixtures.  
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.  
1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 Density is weight per unit volume. It is a key property in the identification, characterization, and quality control of a wide range of materials. Density measurements in terms of weight per gallon are commonly used to check paint quality. If the density is not within specification, there is a good chance that there was a mischarge or other serious problem.  
5.2 This test method is suitable for the determination of density of paint and related products and components when in liquid form. It is particularly applicable when the fluid has too high a viscosity or when a component is too volatile for a density balance determination.  
5.3 This test method provides for the maximum accuracy required for hiding power determinations. It is equally suitable for work in which less accuracy is required, by ignoring the directions for recalibration and consideration of temperature differentials, and using as the container a “weight-per-gallon” cup.  
5.4 Automatic equipment for measuring density is available (see Test Method D4052) from several manufacturers. Such apparatus has been used for resins and latices as well as for oils and solvents. Before such equipment is used for a given product, results must be checked very carefully. Particularly with paints, inks, and resins, there are possibilities of gumming, fouling, and other interferences with operation.
SCOPE
1.1 This test method covers the measurement of density of paints, inks, varnishes, lacquers, and components thereof, other than pigments, when in fluid form.  
1.2 For higher precision when working with nonpigmented materials (drying oils, varnishes, resins and related materials), Test Method D1963 can be used to determine specific gravity and, thence, density.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3.1 Exception—The values for density are to be stated in inch-pound units.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. A specific precaution statement is given in 8.1.1.1.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The yield stress of a material is a measure of the amount of force required to initiate movement of that material in a pipe, through a pump, or from nozzle. The yield stress also characterizes the ability of the material to maintain particles in suspension. Along with viscosity measurements, yield stress measurements have been useful in establishing root causes of flow problems such as excessive orange peel and sagging and in explaining resistance to such problems. After a coating has been applied, flow and leveling tends to be inversely related to yield stress and sag resistance tends to be directly related to yield stress. The ability of an automotive basecoat to keep aluminum and/or mica flakes oriented has been related to yield stress (direct relationship).
SCOPE
1.1 These test methods cover three approaches for determining yield stress values of paints, inks and related liquid materials using rotational viscometers. The first method uses a rotational viscometer with coaxial cylinder, cone/plate, or plate/plate geometry. The second method uses a rheometer operating in controlled stress mode with similar geometries. The third method uses a viscometer with a vane spindle.  
1.2 A non-rotational technique, the falling needle viscometer (FNV), also can be used to measure yield stress values in paints, inks and related materials. See Test Methods D5478, Test Method D, Yield Stress Determination for details.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Test Method A is used for determining the apparent viscosity at a given rotational speed, although viscosities at two or more speeds give better characterization of a non-Newtonian material than does a single viscosity measurement.  
3.2 With Test Methods B and C, the extent of shear thinning is indicated by the drop in viscosity with increasing rotational speed. The degree of thixotropy is indicated by comparison of viscosities at increasing and decreasing rotational speeds (Test Method B), viscosity recovery (Test Method B), or viscosities before and after high shear (combination of Test Methods B and C). The high-shear treatment in Test Method C approximates shearing during paint application. The viscosity behavior measured after high shear is indicative of the characteristics of the paint soon after application.
SCOPE
1.1 These test methods cover the determination of the apparent viscosity and the shear thinning and thixotropic properties of non-Newtonian materials in the shear rate range from 0.1 s−1 to 50 s−1 using a rotational viscometer operating in a fluid contained in a 600 mL low form Griffin beaker.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The viscosity of paint, inks and many related liquid materials is dependent on temperature. It is useful to know the extent of this dependence. One use of such information is to prepare a viscosity-temperature table or curve. Then, if ambient conditions do not allow the measurement of viscosity at the exact temperature stated in a specification or regulation, the viscosity measured at ambient temperature can be used to determine the viscosity at the temperature of interest through the use of the previously prepared table or curve. Viscosity measurements that cover a range of shear rates as well as temperatures could include shear rates associated with paint application or allow extrapolation to such shear rates. This information would enable a producer or user to estimate the effect on application of heating the paint.
SCOPE
1.1 These test methods cover the use of rotational viscometers to determine the dependence of apparent viscosity of paints, inks and related liquid materials on temperature. The first method uses a standard rotational viscometer with concentric cylinder geometry running at a fixed rotational speed as the temperature is increased or decreased. The second method uses a rotational viscometer with cone and plate geometry running at a fixed rotational speed as the temperature is increased or decreased. The third method uses concentric cylinder or cone/plate geometry operated with a shear rate ramp at several discrete temperatures.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard may involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is useful for the determination of package and application viscosities of paints and other coatings. It is limited to Newtonian or near-Newtonian liquids.  
5.2 This test method may be used similarly to ISO 2431 in conjunction with flashpoint to determine the hazard grouping of viscous liquids in international regulations.
SCOPE
1.1 This test method covers the determination of the flow time (viscosity) of Newtonian and near-Newtonian paints, and related coatings and products using ISO capillary flow cups.  
Note 1: If the liquid is non-Newtonian, that is shear-thinning or thixotropic, Test Methods D2196 should be used.  
1.2 The cup-orifice combination (ISO cup with orifice diameter of 3 mm, 4 mm, 5 mm, or 6 mm)2 is selected to provide an efflux time with the range of 20 to 100 s and viscosities up to 700 cSt (700 mm2/s). The most commonly used cup is the one with the 4-mm orifice.  
1.3 This test method is limited to testing materials for which the breakpoint of the flow from the orifice of the flow cup can be determined with certainty. This point is difficult to determine and reproduce for materials with flow times in excess of 100 s due to slowing-down effects.  
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
Note 2: The International Civil Aviation Organization (ICAO) and the International Maritime Organization (IMO) include in their regulations a similar test (ISO 2431) to determine the viscosity of hazardous viscous liquids. The viscosity is then used to place these liquids in a hazard packaging group depending on their viscosity/flashpoint relationship. The U. S. Department of Transportation permits the use of these regulations for transhipment of hazardous material within the U.S. when bound for foreign destinations.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 The results obtained with a mechanical muller do not necessarily correlate directly with an industrial situation where different dispersing conditions exist. However, dispersion with a mechanical muller is a quick and inexpensive way to prepare specimens for testing the color and strength of a pigment for routine quality control.  
5.2 By following the procedure described in Appendix X1, the conditions for achieving the maximum practical degree of dispersion with a mechanical muller may be determined. Any color and strength tests done with the dispersions should be carried out under these conditions.
SCOPE
1.1 This practice is intended to be used to disperse a chromatic pigment for subsequent testing.  
1.2 This practice does not apply to white pigments.
Note 1: The dispersion portion of Test Method D3022 is similar to this practice, but it utilizes a miniature sandmill rather than a mechanical muller, to disperse the chromatic pigment.
Note 2: The dispersion portions of Test Methods D332 and D2745 are similar to this practice, but they are intended for use with white pigments, rather than chromatic pigments.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 8.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 The viscosity value obtained by this test method gives information about the flow properties of the material under high-shear conditions similar to those encountered during application: brushing (see Test Method D4958), spraying, electrostatic disk, or roll coating.  
4.2 This test method is suitable for all paints and varnishes whether they are Newtonian in behavior or not. However, due to the narrow gap between the stationary and rotary parts of high-shear viscometers, this test method is more reproducible for paints having finer pigment dispersions as determined by Test Method D1210.
SCOPE
1.1 This test method covers the determination of the viscosity of paints, varnishes, and related products at a rate of shear of 12 000 s−1.  
1.2 Paints and varnishes that dry very rapidly may not give reproducible results with this test method. Measurements made at elevated temperatures may also give poor precision due to loss of volatiles and to drying.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method provides values that are useful in specifying and controlling the consistency of paints, such as consumer or trade sales products.
SCOPE
1.1 This test method covers the measurement of Krebs Unit (KU) viscosity to evaluate the consistency of paints and related coatings using the Stormer-type viscometer.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 This test method is useful for the determination of package and application viscosities of a number of paints and other coatings and in the thinning of these materials, but is limited to Newtonian or near-Newtonian liquids.  
5.2 There are other types of apparatus for measuring viscosity in the laboratory that produce more accurate results.
SCOPE
1.1 This test method covers the determination of the viscosity of Newtonian or near-Newtonian paints, varnishes, lacquers, and related liquid materials with the Ford-type efflux viscosity cup. If the material is non-Newtonian, that is, shear-thinning or thixotropic, Test Method D2196 should be used.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 These tests are suitable for testing paints adjusted for compatibility with various electrostatic spray coating applications, and by their use, spray performance can be optimized.
SCOPE
1.1 These test methods cover the determination of specific resistance (resistivity) of liquid paints, solvents, and other fluids in the range of 0.6 to 2640 MΩ-cm.  
1.2 Test Method A describes a procedure for making resistance tests with a commonly used paint application test assembly (Fig. 1 and Fig. 2).
FIG. 1 Analog Paint Application Test Assembly  
FIG. 2 Diagram of Digital Application Test Assembly  
1.3 Test Method B describes a procedure for making resistance tests with a conductivity meter (Fig. 3).
FIG. 3 Conductivity Meter  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 These test methods are applicable for measuring the rheological properties of varnishes and paints. In particular, the low to moderate shear rate measurements provide information related to sag resistance, leveling, etc.
SCOPE
1.1 These test methods cover the measurement of the viscosity of Newtonian and non-Newtonian liquids. These test methods are applicable to liquids having viscosities in the range from 5 × 10−4 to 103 Pa·s (0.5 to 106 cP). The shear rate range is dependent upon the needle used and viscosity of the liquid and may vary from 10−4 to 103 s−1. With an extension bar and applied weight, a shear rate of 104 s–1 may be achieved.  
1.2 The yield stress of liquids having this property may also be determined.  
1.3 These test methods consist of determining liquid viscosities of Newtonian and non-Newtonian fluids (clear or opaque) by measuring the steady-state (constant) or terminal velocities of cylindrical needles as they fall through the test liquid under the influence of gravity. Yield stresses of non-Newtonian liquids may be measured using the same procedure.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Test Method A is used for determining the apparent viscosity at a given rotational speed, although viscosities at two or more speeds give better characterization of a non-Newtonian material than does a single viscosity measurement.  
3.2 With Test Methods B and C, the extent of shear thinning is indicated by the drop in viscosity with increasing rotational speed. The degree of thixotropy is indicated by comparison of viscosities at increasing and decreasing rotational speeds (Test Method B), viscosity recovery (Test Method B), or viscosities before and after high shear (combination of Test Methods B and C). The high-shear treatment in Test Method C approximates shearing during paint application. The viscosity behavior measured after high shear is indicative of the characteristics of the paint soon after application.
SCOPE
1.1 These test methods cover the determination of the apparent viscosity and the shear thinning and thixotropic properties of non-Newtonian materials in the shear rate range from 0.1 to 50 s−1 using a rotational viscometer operating in a fluid contained in a 600 mL low form Griffin beaker.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
4.1 This test has been used to measure viscosities of automotive topcoats in place of No. 4 Ford cup measurements and has provided an equivalent ability to evaluate whether the paint meets specifications and is sprayable.  
4.2 The method could be considered as an alternative to No. 4 Ford cup and other efflux cup measurements for other products as well.  
4.3 The type of viscometer described in this method gives better temperature control than Ford and other efflux cups and is expected to give better precision.  
4.4 This test method is suitable for all paints and related materials whether they are Newtonian in behavior or not.
SCOPE
1.1 This test method covers the determination of the viscosity of paints and related products using a cone/plate viscometer at a shear rate of 500 s-1.  
1.2 Viscosity values obtained by this method may be used as an alternative to results from No. 4 Ford cup measurements. The values from this method do not replicate Ford cup results, but can be used for quality control, producer-user specifications and viscosity reduction in the same manner that Ford cups are used.  
1.3 If viscosity at a higher shear rate is needed, Test Method D4287, which describes viscosity measurement at 10 000 s-1 to 12 000 s-1 may be used.  
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are provided for information only and are not considered standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
3.1 Test Method A is used for determining the apparent viscosity at a given rotational speed, although viscosities at two or more speeds give better characterization of a non-Newtonian material than does a single viscosity measurement.  
3.2 With Test Methods B and C, the extent of shear thinning is indicated by the drop in viscosity with increasing rotational speed. The degree of thixotropy is indicated by comparison of viscosities at increasing and decreasing rotational speeds (Test Method B), viscosity recovery (Test Method B), or viscosities before and after high shear (combination of Test Methods B and C). The high-shear treatment in Test Method C approximates shearing during paint application. The viscosity behavior measured after high shear is indicative of the characteristics of the paint soon after application.
SCOPE
1.1 These test methods cover the determination of the apparent viscosity and the shear thinning and thixotropic properties of non-Newtonian materials in the shear rate range from 0.1 to 50 s−1 using a rotational viscometer operating in a fluid contained in a 600 mL low form Griffin beaker.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 A significant feature of this practice is the ability to survey coating rheology over a broad range of shear rates with the same bench viscometers and test protocol that paint formulators and paint quality control (QC) analysts routinely use. By using this procedure, measurement of the shear rheology of a coating is possible without using an expensive laboratory rheometer, and performance predictions can be made based on those measurements.  
5.2 Low-Shear Viscosity (LSV)—The determination of low-shear viscosity in this practice can be used to predict the relative “in-can” performance of coatings for their ability to suspend pigment or prevent syneresis, or both. The LSV can also predict relative performance for leveling and sag resistance after application by roll, brush or spray. Fig. 1 shows the predictive low-shear viscosity relationships for several coatings properties.
FIG. 1 Low Shear Viscosity (LSV)  
5.3 Mid-Shear Viscosity (MSV)—The determination of MSV (coating consistency) in this practice is often the first viscosity obtained. This viscosity reflects the coatings resistance to flow on mixing, pouring, pumping, or hand stirring. Architectural coatings nearly always have a target specification for mid-shear viscosity, which is usually obtained by adjusting the level of thickener in the coating. Consequently, mid-shear viscosity is ideally a constant for a given series of coatings being tested to provide meaningful comparisons of low-shear and high-shear viscosity. With viscosities at the same KU value, MSV can also be used to obtain the relative Mid-Shear Thickener Efficiency (MSTE) of different thickeners in the same coating expressed as lb thickener/100 gal wet coating or g thickener/L wet coating.  
5.4 High-Shear Viscosity (HSV)—High-shear viscosity in this practice is a measure of the coatings resistance to flow on application by brush or roller, which is often referred to as brush-drag or rolling resistance respectively. This viscosity rela...
SCOPE
1.1 This practice describes a popular industry protocol for the rheological characterization of waterborne architectural coatings using three commonly used rotational bench viscometers. Each viscometer operates in a different shear rate regime for determination of coating viscosity at low shear rate, mid shear rate, and at high shear rate respectively as defined herein. General guidelines are provided for predicting some coating performance properties from the viscosity measurements made. With appropriate correlations and subsequent modification of the performance guidelines, this practice has potential for characterization of other types of aqueous and non-aqueous coatings.  
1.2 The values in common viscosity units (Krebs Units, KU and Poise, P) are to be regarded as standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT
This test method covers the procedures for determining the viscosity of transparent liquids by bubble time method. The transparent liquids should be free from crystalline or gel particles. Test apparatus include a constant-temperature bath, standard viscosity tubes, a series of standard viscosity tubes as reference standards, timing device, tube racks, and viscosity tube corks.
SCOPE
1.1 This test method covers the determination of the viscosity in bubble seconds by timing. The bubble seconds are approximately equal to stokes for most liquids.  
1.2 The test method is applicable to transparent liquids that are free from crystalline or gel particles.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 By following this test method, the particle size, particle size distribution and particle shape of particulates in liquid paint and pigment dispersions can be measured.  
5.2 Particle size, particle size distribution and particle shape have a great effect on the color, opacity and gloss of paints. Reproducing these characteristics is critical to the quality and performance of the paint produced.  
5.3 The dynamic imaging instrument is useful during manufacturing to detect oversize particles as well as the required size distribution of particles in order to provide quality and consistency from batch to batch.
SCOPE
1.1 This test method covers the determination of particle size distribution and particle shape of liquid paints and pigmented liquid coatings by Dynamic Image Analysis. This method includes the reporting of particles ≥1 µm in size and up to 300 µm in size.
Note 1: Shape is used to classify particles, droplets and bubbles and is not a reporting requirement.
Note 2: The term paint(s) as used in this document includes liquid paint and liquid pigmented coatings.  
1.1.1 Some paints may be too viscous to flow through the imaging instrument without dilution which may be used to help the paint flow as long as significant contamination is not introduced into the paint.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE
5.1 A significant feature of this practice is the ability to survey coating rheology over a broad range of shear rates with the same bench viscometers and test protocol that paint formulators and paint quality control (QC) analysts routinely use. By using this procedure, measurement of the shear rheology of a coating is possible without using an expensive laboratory rheometer, and performance predictions can be made based on those measurements.  
5.2 Low-Shear Viscosity (LSV)—The determination of low-shear viscosity in this practice can be used to predict the relative “in-can” performance of coatings for their ability to suspend pigment or prevent syneresis, or both. The LSV can also predict relative performance for leveling and sag resistance after application by roll, brush or spray. Fig. 1 shows the predictive low-shear viscosity relationships for several coatings properties.
SCOPE
1.1 This practice covers a popular industry protocol for the rheological characterization of waterborne architectural coatings using three commonly used rotational bench viscometers. Each viscometer operates in a different shear rate regime for determination of coating viscosity at low shear rate, mid shear rate, and at high shear rate respectively as defined herein. General guidelines are provided for predicting some coating performance properties from the viscosity measurements made. With appropriate correlations and subsequent modification of the performance guidelines, this practice has potential for characterization of other types of aqueous and non-aqueous coatings.  
1.2 The values in common viscosity units (Krebs Units, KU and Poise, P) are to be regarded as standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 The oil absorption value obtained by this test method provides information about the vehicle demand of the pigment when it is used in a pigment paste. Oil absorption values can be used to characterize batches of a given pigment.  
4.2 This test method differs from Test Method D281 in that D281 requires a vigorous rubbing action whereas this test method involves only a gentle stirring and folding of the pigment. Because the end points are different, the values obtained from the two test methods generally differ.
SCOPE
1.1 This test method covers the determination of oil absorption of pigments by the Gardner-Coleman procedure.2  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
3.1 High speed dispersion is a commonly used dispersion method in the coatings industry. For the purpose of this practice, “high speed” would normally be understood to be a range of RPM between 3 000 and 10 000. This practice provides a reference for its use, so that a producer and user can standardize on an incorporation technique. This will minimize differences in the millbase, and allow the interested parties to concentrate on the physical, chemical, or optical methods to be run.
SCOPE
1.1 This practice covers the dispersion of pigments using a laboratory size high-speed impeller mill. It is similar in technical content to ISO 8780-3.
Note 1: This practice is restricted to mill bases of moderately high viscosity due to either high vehicle concentration or high pigment concentration, or both, which can produce high shear force. It is not intended to provide a means of formulating either pilot plant or full-scale mill base compositions (scaling up the process from laboratory equipment to factory mills is not simple).  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 The oil absorption value obtained by this test method gives information about the vehicle demand of the pigment when it is used in a pigment paste. Oil absorption values can be used to characterize pigments or batches of a given pigment.  
4.2 This test method differs from Test Method D1483 in that D1483 involves only a gentle stirring and folding of the pigment, whereas this test method requires a thorough rubbing action. Because the end points are different, the values obtained from the two test methods generally differ.
SCOPE
1.1 This test method covers the determination of the oil absorption of pigments by the spatula rub-out technique.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 Viscosity is a measure of the fluidity of a material. Viscosity data are useful in the determination of the ease of stirring, pumping, dip coating, or other flow-related properties of paints and related fluids.  
5.2 This type of cup is used to measure viscosity because it is easy to use, robust, and may be used in tanks, reservoirs, and reactors.  
5.3 There are other types of apparatus for measuring viscosity in the laboratory that provide better precision and bias, including the Ford viscosity cup (Test Method D1200), and the rotational viscometer (Test Methods D2196).  
5.4 Certain higher shear rate devices such as cone/plate viscometers (Test Method D4287) provide more information about sprayability, roll coatability, and other high-shear rate related properties of coatings.
SCOPE
1.1 This test method covers the determination of viscosity of paints, varnishes, lacquers, inks, and related liquid materials by dip-type viscosity cups. This test method is recommended for viscosity control work within one plant or laboratory and should be used to check compliance with specifications only when sufficient controls have been instituted to ensure adequate comparability of results.  
1.2 Viscosity cups are designed for testing of Newtonian and near-Newtonian liquids. If the test material is non-Newtonian, for example, shear-thinning or thixotropic, another method, such as Test Methods D2196, should be used. Under controlled conditions, comparisons of the viscosity of non-newtonian materials may be helpful, but viscosity determination methods using controlled shear rate or shear stress are preferred.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
3.1 Paints, if not formulated or processed properly may settle excessively. Paint that settles excessively is difficult to reincorporate into the paint system causing time delays or valuable pigment being left in the drum. This test method is an attempt to evaluate the degree of settling caused by the accelerated Test Method D1309. This very subjective method of evaluation in conjunction with the variables of Test Method D1309 raises questions as to the usefulness of the results for specification compliance.
SCOPE
1.1 This test method covers the determination of the degree of pigment suspension and ease of remixing a shelf-aged sample of paint to a homogeneous condition suitable for the intended use.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
3.1 Test Method A is used for determining the apparent viscosity at a given rotational speed, although viscosities at two or more speeds give better characterization of a non-Newtonian material than does a single viscosity measurement.  
3.2 With Test Methods B and C, the extent of shear thinning is indicated by the drop in viscosity with increasing rotational speed. The degree of thixotropy is indicated by comparison of viscosities at increasing and decreasing rotational speeds (Test Method B), viscosity recovery (Test Method B), or viscosities before and after high shear (combination of Test Methods B and C). The high-shear treatment in Test Method C approximates shearing during paint application. The viscosity behavior measured after high shear is indicative of the characteristics of the paint soon after application.
SCOPE
1.1 These test methods cover the determination of the apparent viscosity and the shear thinning and thixotropic properties of non-Newtonian materials in the shear rate range from 0.1 to 50 s−1 using a rotational viscometer operating in a fluid of “infinite” dimensions.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 This test method is useful for the determination of package and application viscosities of a number of paints and other coatings and in the thinning of these materials, but is limited to Newtonian or near-Newtonian liquids.  
5.2 There are other types of apparatus for measuring viscosity in the laboratory that produce more accurate results.
SCOPE
1.1 This test method covers the determination of the viscosity of Newtonian or near-Newtonian paints, varnishes, lacquers, and related liquid materials with the Ford-type efflux viscosity cup. If the material is non-Newtonian, that is, shear-thinning or thixotropic, Test Method D2196 should be used.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 The viscosity value obtained by this test method gives information about the flow properties of the material under high-shear conditions similar to those encountered during application: brushing (see Test Method D4958), spraying, electrostatic disk, or roll coating.  
4.2 This test method is suitable for all paints and varnishes whether they are Newtonian in behavior or not. However, due to the narrow gap between the stationary and rotary parts of high-shear viscometers, this test method is more reproducible for paints having finer pigment dispersions as determined by Test Method D1210.
SCOPE
1.1 This test method covers the determination of the viscosity of paints, varnishes, and related products at a rate of shear of 12 000 s−1.  
1.2 Paints and varnishes that dry very rapidly may not give reproducible results with this test method. Measurements made at elevated temperatures may also give poor precision due to loss of volatiles and to drying.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 These methods provide data that are useful in evaluating the effectiveness of surface active agents in reducing surface tension. In addition, surface tension data can predict interactions between liquids and solid surfaces or other liquids and can be used to establish wetting properties of paints, solvents, and other liquids.  
5.2 A number of laboratories have found the Wilhelmy plate to be easier to use, easier to clean and generally better for use with pigmented paints.
SCOPE
1.1 These test methods cover the determination of surface tension and interfacial tension of a variety of liquid materials, including but not restricted to paints, solvents, and solutions of surface-active agents, as defined in Terminology D459. Four methods are covered as follows:
Method A—Surface Tension by du Noüy ring.
Method B—Interfacial Tension by du Noüy ring.
Method C—Surface Tension by Wilhelmy plate.
Method D—Interfacial Tension by Wilhelmy plate.  
1.2 Method A originally was written primarily to cover aqueous solutions of surface-active agents, but is also applicable to aqueous paints, nonaqueous solutions (including paints) and mixed solvent solutions.  
1.3 Method B is applicable to two-phase solutions. More than one solute component may be present, including solute components that are not in themselves surface-active.  
1.4 Method C is applicable to surface active liquids and, unlike du Noüy ring, no buoyancy corrections are needed and results are not affected by moderate viscosities (1-10 Pa-sec) of the liquid. It is the recommended method for use with paints and resin solutions.  
1.5 Method D is applicable to two-phase solutions and mixtures.  
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.

SIGNIFICANCE AND USE
5.1 This test method provides values that are useful in specifying and controlling the consistency of paints, such as consumer or trade sales products.
SCOPE
1.1 This test method covers the measurement of Krebs Unit (KU) viscosity to evaluate the consistency of paints and related coatings using the Stormer-type viscometer.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
5.1 This test method is useful for the determination of package and application viscosities of paints and other coatings. It is limited to Newtonian or near-Newtonian liquids.  
5.2 This test method may be used similarly to ISO 2431 in conjunction with flashpoint to determine the hazard grouping of viscous liquids in international regulations.
SCOPE
1.1 This test method covers the determination of the flow time (viscosity) of Newtonian and near-Newtonian paints, and related coatings and products using ISO capillary flow cups.  
Note 1: If the liquid is non-Newtonian, that is shear-thinning or thixotropic, Test Methods D2196 should be used.  
1.2 The cup-orifice combination (ISO cup with orifice diameter of 3 mm, 4 mm, 5 mm, or 6 mm)2 is selected to provide an efflux time with the range of 20 to 100 s and viscosities up to 700 cSt (700 mm2/s). The most commonly used cup is the one with the 4-mm orifice.  
1.3 This test method is limited to testing materials for which the breakpoint of the flow from the orifice of the flow cup can be determined with certainty. This point is difficult to determine and reproduce for materials with flow times in excess of 100 s due to slowing-down effects.  
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.5 This standard does not purport to address the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
Note 2: The International Civil Aviation Organization (ICAO) and the International Maritime Organization (IMO) include in their regulations a similar test (ISO 2431) to determine the viscosity of hazardous viscous liquids. The viscosity is then used to place these liquids in a hazard packaging group depending on their viscosity/flashpoint relationship. The U. S. Department of Transportation permits the use of these regulations for transhipment of hazardous material within the U.S. when bound for foreign destinations.

SIGNIFICANCE AND USE
5.1 Viscosity is a measure of the fluidity of a material. Viscosity data are useful in the determination of the ease of stirring, pumping, dip coating, or other flow-related properties of paints and related fluids.  
5.2 This type of cup is used to measure viscosity because it is easy to use, robust, and may be used in tanks, reservoirs, and reactors.  
5.3 There are other types of apparatus for measuring viscosity in the laboratory that provide better precision and bias, including the Ford viscosity cup (Test Method D1200), and the Brookfield viscometer (Test Methods D2196).  
5.4 Certain higher shear rate devices such as cone/plate viscometers (Test Method D4287) provide more information about sprayability, roll coatability, and other high-shear rate related properties of coatings.
SCOPE
1.1 This test method covers the determination of viscosity of paints, varnishes, lacquers, inks, and related liquid materials by dip-type viscosity cups. This test method is recommended for viscosity control work within one plant or laboratory and should be used to check compliance with specifications only when sufficient controls have been instituted to ensure adequate comparability of results.  
1.2 Viscosity cups are designed for testing of Newtonian and near-Newtonian liquids. If the test material is non-Newtonian, for example, shear-thinning or thixotropic, another method, such as Test Methods D2196, should be used. Under controlled conditions, comparisons of the viscosity of non-newtonian materials may be helpful, but viscosity determination methods using controlled shear rate or shear stress are preferred.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 In making pigmented products, the pigment is usually dispersed in a portion of the vehicle in some sort of mill. At this stage, it is necessary to be able to judge if the pigment agglomerates have been sufficiently broken up so as not to interfere with the smoothness of the finished coating film. This test method describes a way of making this judgment.
SCOPE
1.1 This test method covers measurement of the degree of dispersion (commonly referred to as “fineness of grind”) of the pigment in a pigment-vehicle system such as liquid coatings and their intermediates. It may also be used to assess the inclusion of particulates by a cleanliness (or texture) rating.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

SIGNIFICANCE AND USE
4.1 Physical constants of paints and coatings are required in all aspects of their formulation, manufacture and use. This practice demonstrates standard methods agreed upon for calculating formulation values for some of these physical constants. The calculations are the same for either metric or inch/pound units.  
4.2 These formula values may not be used to replace measured values required by government regulations unless specifically stated in the governing documents.  
4.3 Some regulations allow compliance determination using formulation data instead of analytical data. This formulation data may not yield the same results as the required analytical method, which could be performed on a sample from any production batch of the coating. In these cases, the user may wish to compare formulation data to analytical data and develop a factor that adjusts for variability of raw materials, variability of production batches, cure volatiles, and variability of the analytical methods.
SCOPE
1.1 This practice covers procedures commonly used in the paint industry to formulate paints and coating materials. It describes procedures for calculating formulation values for weight solids, volume solids, solvent content, volatile organic compound (VOC) content, hazardous air pollutant (HAP) content, and density of liquid paints and coatings. These values are calculated from basic formulation data. These calculations may be related to either as-supplied (unreduced) or as-applied (reduced) coating materials, including multicomponent types.  
1.2 These calculated, formulation-based values may or may not be acceptable for VOC regulatory purposes, depending on the specific wording of the applicable regulation. Some regulations require analysis of the coating. Some rules allow the use of formulation data, however, some adjustments may be needed to the values calculated in this practice before they are used for regulatory purposes (see 4.3).  
1.3 For purposes of this practice, it is assumed that volatile components evaporate and the materials that remain are identified as coating solids. For example, solvents are normally used to adjust viscosity for application and appearance of the coating. Other liquid materials, such as plasticizers, reactive diluents, etc., that are expected to be retained in the dried film to affect the final physical properties should be classified as part of the coating solids. Standards such as Test Methods D2369, D4758, D5403 and Guide D2832 may be used to determine volatile or nonvolatile content of specific components. For purposes of this practice it is assumed that the blended formulation behaves as an ideal solution with no volume change on mixing (see 6.2).  
1.4 Volatile by-products of cross-linking reactions (cure volatiles) are not considered in these calculations since the object of this practice is to define paint physical constants based on formulation information. Variations in raw materials, variations in the production processes, test methods, and test method accuracy are not taken into account in these calculations.  
1.5 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. However, they may be readily converted into SI units, if required by the user (for example, see Note 4).

SIGNIFICANCE AND USE
5.1 Density is weight per unit volume. It is a key property in the identification, characterization, and quality control of a wide range of materials. Density measurements in terms of weight per gallon are commonly used to check paint quality. If the density is not within specification, there is a good chance that there was a mischarge or other serious problem.  
5.2 This test method is suitable for the determination of density of paint and related products and components when in liquid form. It is particularly applicable when the fluid has too high a viscosity or when a component is too volatile for a density balance determination.  
5.3 This test method provides for the maximum accuracy required for hiding power determinations. It is equally suitable for work in which less accuracy is required, by ignoring the directions for recalibration and consideration of temperature differentials, and using as the container a “weight-per-gallon” cup.  
5.4 Automatic equipment for measuring density is available (see Test Method D4052) from several manufacturers. Such apparatus has been used for resins and latices as well as for oils and solvents. Before such equipment is used for a given product, results must be checked very carefully. Particularly with paints, inks, and resins, there are possibilities of gumming, fouling, and other interferences with operation.
SCOPE
1.1 This test method covers the measurement of density of paints, inks, varnishes, lacquers, and components thereof, other than pigments, when in fluid form.  
1.2 For higher precision when working with nonpigmented materials (drying oils, varnishes, resins and related materials), Test Method D1963 can be used to determine specific gravity and, thence, density.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3.1 Exception—The values for density are to be stated in inch-pound units.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. A specific precaution statement is given in 8.1.1.1.