EN 17813:2023

Environmental solid matrices - Determination of halogens and sulfur by oxidative pyrohydrolytic combustion followed by ion chromatography

This document specifies an empirical method for the simultaneous direct determination of the fluorine, chlorine, bromine, and sulfur content in environmental solid matrices by oxidative pyrohydrolytic combustion at (1 050 ± 50) °C, followed by ion chromatography. The method is applicable for the determination of concentrations ≥ 10 mg/kg of each element based on dry matter. The upper limit and exact concentration range covered depends on the blank levels of the instrumentation and the capacity of the chromatographic separation column used for determination.
NOTE 1   Simultaneous determination of iodine content is possible but currently not validated.
NOTE 2   Other detection methods can be applied if validated.

Feststoffe in der Umwelt - Bestimmung von Halogenen und Schwefel durch oxidative pyrohydrolytische Verbrennung, gefolgt von Ionenchromatographie

Dieses Dokument legt ein Konventionsverfahren für die gleichzeitige direkte Bestimmung des Gehalts an Fluor, Chlor, Brom und Schwefel in Feststoffen in der Umwelt durch oxidative pyrohydrolytische Verbrennung bei (1 050 ± 50) °C, gefolgt von Ionenchromatographie fest. Das Verfahren ist anwendbar für die Bestimmung von Konzentrationen ≥ 10 mg/kg jedes Elements, bezogen auf die Trockenmasse. Die Höchstgrenze und der exakte Konzentrationsbereich, der abgedeckt wird, hängen von den Blindwerten der Geräte und der Kapazität der für die Bestimmung verwendeten chromatographischen Trennsäule ab.
ANMERKUNG 1   Die gleichzeitige Bestimmung des Iodgehalts ist möglich, aber derzeit nicht validiert.
ANMERKUNG 2   Andere Detektionsmethoden können verwendet werden, sofern sie validiert sind.

Matrices environnementales solides - Méthode de dosage des halogènes et du soufre par combustion pyrohydrolytique oxydative suivie d’une analyse par chromatographie ionique

Le présent document spécifie une méthode empirique de dosage, direct et simultané, du fluor, du chlore, du brome et du soufre dans des matrices environnementales solides, par combustion pyrohydrolytique oxydative à une température de (1 050 ± 50) °C, suivie d’une analyse par chromatographie ionique. Cette méthode s'applique à la détermination, pour chaque élément, de concentrations supérieures ou égales à 10 mg/kg, en masse de matière sèche. La limite supérieure et la plage de concentration exacte couverte dépendent des niveaux de blanc des appareils et de la capacité de la colonne de séparation chromatographique utilisée pour le dosage.
NOTE 1   Le dosage simultané de l'iode est possible, mais non validé à l'heure actuelle.
NOTE 2   D’autres méthodes de détection peuvent être appliquées, dès lors qu’elles sont validées.

Trdni matriksi z vidika okolja - Določanje halogenov in žvepla z ionsko kromatografijoi po oksidativnem pirohidrolitskem sežigu

General Information

• Status: Published
• Publication Date: 24-Oct-2023
• ICS: 71.040.40 - Chemical analysis
• ICS: 71.040.50 - Physicochemical methods of analysis
• Technical Committee: CEN/TC 444 - Environmental characterization
• Drafting Committee: CEN/TC 444/WG 3 - Inorganic analysis
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 25-Oct-2023
• Due Date: 06-Dec-2022
• Completion Date: 25-Oct-2023
• Directive: 2000/76/EC - Directive 2000/76/EC of the European Parliament and of the Council of 4 December 2000 on the incineration of waste
• Directive: 99/31/EC - Landfill of waste
• Ref Project: SIST EN 17813:2024 - Environmental solid matrices - Determination of halogens and sulfur by oxidative pyrohydrolytic combustion followed by ion chromatography

Standards Content (Sample)

SLOVENSKI STANDARD
oSIST prEN 17813:2022
01-januar-2022
Matriksi z vidika okolja - Določevanje halogenov in žvepla z ionsko kromatografijo
ali komplementarnimi/dopolnilnimi metodami po pirohidrolitskem sežigu
Environmental matrices - Halogens and sulfur by oxidative pyrohydrolytic combustion
followed by ion chromatography detection and complementary determination methods
Umweltbezogene Charakterisierung fester Matrices - Halogene und Schwefel durch
oxidative pyrohydrolytische Verbrennung, gefolgt von ionenchromatographischer
Detektion und komplementären Bestimmungsmethoden
Ta slovenski standard je istoveten z: prEN 17813
ICS:
71.040.40 Kemijska analiza Chemical analysis
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
oSIST prEN 17813:2022 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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oSIST prEN 17813:2022

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oSIST prEN 17813:2022


DRAFT
EUROPEAN STANDARD
prEN 17813
NORME EUROPÉENNE

EUROPÄISCHE NORM

January 2022
ICS 71.040.40; 71.040.50
English Version

Environmental matrices - Halogens and sulfur by oxidative
pyrohydrolytic combustion followed by ion
chromatography detection and complementary
determination methods

This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 444.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2022 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 17813:2022 E
worldwide for CEN national Members.

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oSIST prEN 17813:2022
prEN 17813:2022 (E)
Contents      Page
European foreword . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 Interferences . 5
5.1 Interferences during combustion . 5
5.2 Interferences during absorption . 6
5.3 Interferences during ion chromatography . 6
6 Reagents and gases. 6
6.1 General. 6
6.2 Reagents fo
...